SUCRA(さくら: Saitama University Cyber Repository of Academic Resources)は、埼玉大学に在籍する研究者の学術雑誌論文、紀要論文、科学研究費補助金成果報告書、学位論文、研究発表プレゼン資料などを登録し、広く世界に発信しています。 埼玉大学に在籍する皆様は、著作物をSUCRAを通じて発信することができます。詳しくは「成果物の登録方法」をご覧ください。
Matsuoka, Koji
Terunuma, Daiyo
Hatano, Ken
Ohtawa, Takumi
Hinou, Hiroshi
Koyama, Tetsuo
Esumi, Yasuaki
Nishimura, Shin-Ichiro
著者 所属
埼玉大学大学院理工学研究科
埼玉大学大学院理工学研究科
埼玉大学大学院理工学研究科
著者 所属(別言語)
Graduate School of Science and Engineering, Saitama University
Graduate School of Science and Engineering, Saitama University
Graduate School of Science and Engineering, Saitama University
A novel anomeric b-thioacetate of an N-acetyllactosamine derivative was efficiently synthesized in high yield from the known 2-azido glycosyl chloride using thioacetic acid as a convenient reagent. The synthesis involved not only an SN2 replacement of the chloride by a carbothiolate anion but also a reductive acetamidation of the azide group. Applications of the thioacetate for glycosidation were demonstrated to provide both O- and S-glycosides in high yields. Furthermore, both intermediates gave a new class of glycoclusters that included thioglycosidic linkages.
Synthesis of a useful anomeric thioacetate of an N-acetyllactosamine derivative and its application
A1001068.pdf
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SUCRAの概要
