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An alternative route for the construction of carbosilane dendrimers uniformly functionalized with lactose or sialyllactose moieties
https://sucra.repo.nii.ac.jp/records/12488
https://sucra.repo.nii.ac.jp/records/12488a678d1bf-cfbe-4a7f-8dfb-8061a84474ea
名前 / ファイル | ライセンス | アクション |
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A1001654.pdf (35.8 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-03-08 | |||||
タイトル | ||||||
タイトル | An alternative route for the construction of carbosilane dendrimers uniformly functionalized with lactose or sialyllactose moieties | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | radical additions | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | thioacetate | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | carbosilane dendrimers | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | sulfide | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | glycodendrimers | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Carbohydrates | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
松岡, 浩司
× 松岡, 浩司× 照沼, 大陽 |
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著者 ローマ字 | ||||||
Matsuoka, Koji | ||||||
著者 ローマ字 | ||||||
Terunuma, Daiyo | ||||||
著者 ローマ字 | ||||||
Oka, Hiroyuki | ||||||
著者 ローマ字 | ||||||
Koyama, Tetsuo | ||||||
著者 ローマ字 | ||||||
Esumi, Yasuaki | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科 | ||||||
著者 所属(別言語) | ||||||
Saitama University, Graduate School of Science and Engineering | ||||||
著者 所属(別言語) | ||||||
Saitama University, Graduate School of Science and Engineering | ||||||
書誌情報 |
Tetrahedron letters 巻 11-Feb, 号 19-Jan, 発行日 2001 |
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年月次 | ||||||
2001 | ||||||
出版者名 | ||||||
出版者 | Elsevier Science Ltd. | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00404039 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1016/S0040-4039(01)00422-1 | |||||
関連サイト | ||||||
内容記述タイプ | Other | |||||
内容記述 | http://www.sciencedirect.com/science/journal/00404039 | http://www.sciencedirect.com/science/journal/00404039 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A new approach for the formation of an acetylthio linkage on aglycon by means of a radical addition of thioacetic acid into the C=C double bond of the aglycon was examined. An introduction of a carbohydrate moiety into carbosilane dendrimers was demonstrated using a one-pot coupling reaction in MeOH¾DMF in the presence of NaOMe via removal of an acetyl group of the acetylthio linkage in the saccharide moieties, producing a thiolate anion and a nucleophilic replacement of the thiolate to dendric alkyl bromide to form carbosilane dendrimers uniformly bearing lactose or sialyllactose moieties through thioether linkages in high yields. | |||||
アクセス条件 | ||||||
Private | ||||||
版 | ||||||
[著者版] | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2007-03-05 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
A1001654 |