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Virtual Device Simulator of Bipolar Photogalvanic Cell
https://sucra.repo.nii.ac.jp/records/12540
https://sucra.repo.nii.ac.jp/records/12540a5c1b88f-3d8e-4215-9741-2f2b13601632
名前 / ファイル | ライセンス | アクション |
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A1002095.pdf (180.9 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-03-09 | |||||
タイトル | ||||||
タイトル | Virtual Device Simulator of Bipolar Photogalvanic Cell | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
タイトル(別言語) | ||||||
その他のタイトル | 二層式光化学電池の仮想デバイスシミュレータの作成 | |||||
著者 |
時田, 澄男
× 時田, 澄男 |
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著者 ローマ字 | ||||||
Tokita, Sumio | ||||||
著者 ローマ字 | ||||||
Shiroishi, Hidenobu | ||||||
著者 ローマ字 | ||||||
Kaburagi, Yuuki | ||||||
著者 ローマ字 | ||||||
Seo, Michiko | ||||||
著者 ローマ字 | ||||||
Hoshi, Takayuki | ||||||
著者 ローマ字 | ||||||
Nomura,Tomoyo | ||||||
著者 ローマ字 | ||||||
Kaneko, Masao | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科 | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
書誌情報 |
Journal of Chemical Software 巻 8, 号 2, 発行日 2002 |
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年月次 | ||||||
2002 | ||||||
出版者名 | ||||||
出版者 | 日本コンピュータ化学会 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09180761 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A virtual bipolar photogalvanic cell was developed using Visual Basic. On the basis of the simulation, it is indicated that the charge separation (kd) and the charge recombination (kr) rate constants can be estimated using the photocurrent response. The thickness of the charge separation region can be anticipated by photocurrentresponse at various layer thicknesses. The increase in diffusion coefficients raises the short-circuit photocurrent to enhance the performance of the photogalvanic cell. An actual device was fabricated usingtris(bipyridine)ruthenium(II) complex ([Ru(bpy)3 2+]) as a sensitizer and Prussian Blue as a mediator. This device worked as a photogalvanic cell: short-circuit photocurrent (JSC), 2.3μA/cm2; open-circuit photovoltage (VOC), 0.118V; fill-factor, 20.5 %. It was shown from the action spectrum that electrons are transferred from [Ru(bpy)3 2+*] to Prussian Blue. The charge separation and the recombination rate constants were estimated, using the virtual device, to be 5 _ 102 mol-1cm3s-1 and 6 _ 109 mol-1cm3s-1, respectively. | |||||
注記 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Copyright 2002 Society of Computer Chemistry,Japan.This paper was published in "Sumio. Tokita, J.Comput. Chem. Jpn., 8(2), 47-54, 2002. The internet address of the above Journal is as follows: http://www.sccj.net/ | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2007-03-05 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
A1002095 |