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Aldol condensation of acyclic ketones with benzaldehyde and subsequent cyclodehydration to form indenes over halide cluster catalysts
https://sucra.repo.nii.ac.jp/records/12974
https://sucra.repo.nii.ac.jp/records/1297421eb81d3-5b00-4cc6-a525-1e3ce31adf79
名前 / ファイル | ライセンス | アクション |
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A1002319.pdf (223.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-12-06 | |||||
タイトル | ||||||
タイトル | Aldol condensation of acyclic ketones with benzaldehyde and subsequent cyclodehydration to form indenes over halide cluster catalysts | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | catalysis by halide cluster | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | tantalum chloride cluster | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | aldol condensation of acetone with benzaldehyde | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | acyclic ketone | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | cyclodehydration to indene | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Kamiguchi, Satoshi
× Kamiguchi, Satoshi× Nishida, Satoru× Takahashi, Ikuko× 黒川, 秀樹× Miura, Hiroshi× 千原, 貞次 |
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著者 ローマ字 | ||||||
Kamiguchi, Satoshi | ||||||
著者 ローマ字 | ||||||
Nishida, Satoru | ||||||
著者 ローマ字 | ||||||
Takahashi, Ikuko | ||||||
著者 ローマ字 | ||||||
Kurokawa, Hideki | ||||||
著者 ローマ字 | ||||||
Miura, Hiroshi | ||||||
著者 ローマ字 | ||||||
Chihara, Teiji | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
独立行政法人理化学研究所先端技術開発支援センター | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
RIKEN | ||||||
書誌情報 |
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 巻 255, 号 1-2, p. 117-122, 発行日 2006 |
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年月次 | ||||||
2006-8 | ||||||
出版者名 | ||||||
出版者 | ELSEVIER SCIENCE BV | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 13811169 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1016/j.molcata.2006.04.005 | |||||
関連サイト | ||||||
内容記述タイプ | Other | |||||
内容記述 | http://www.sciencedirect.com/science/journal/13811169 | http://www.sciencedirect.com/science/journal/13811169 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | When a molecular halide cluster [(Ta6Cl12)C-12(H2O)(4)]-4H(2)O (1)/SiO2 was treated in a helium stream above 200 degrees C, it catalyzed the aldol condensation of acetone with benzaldehyde to yield E-4-phenyl-3-buten-2-one. The bromide cluster of Ta and chloride clusters of Nb, Mo, and W of the same octahedral metal framework also catalyzed the reaction. 3,3-Dimethyl-2-butanone combined with benzaldehyde similarly yielded the corresponding aldol condensation product over 1/SiO2 at 400 degrees C. On the other hand, 3-pentanone combined with benzaldehyde provided indenes such as E- and Z-1-ethylidene-2-methylindene and 2-methyl-3-vinylindene of the same carbon skeletal structure, which would be formed by cyclodehydration of the aldol condensation product, E-2-methyl-1-phenyl-1-penten-3-one. One of the advantages of halide cluster catalysts is thermal stability, and high temperatures above 350 degrees C promoted the cyclodehydration. (c) 2006 Elsevier B.V. All rights reserved. | |||||
版 | ||||||
[著者版] | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2007-12-06 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
A1002319 |