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Department of Functional Materials Science, Saitama University
Department of Functional Materials Science, Saitama University
Department of Functional Materials Science, Saitama University
Department of Functional Materials Science, Saitama University
Department of Functional Materials Science, Saitama University
NHK Science and Technical Research Laboratories
NHK Science and Technical Research Laboratories
Department of Functional Materials Science, Saitama University
雑誌名
Molecular Crystals and Liquid Crystals
発行年
2010
出版者名
Taylor & Francis
DOI
info:doi/10.1080/15421401003594719
抄録
By doping 1,1-dimethyl-2,5-bis(N,N-dimethylaminophenyl)-3,4-diphenylsilole (silole-A) in poly(9,9- dioctylfluorene-alt-benzothiadiazole) (F8BT), an improved photoconductive characteristics was observed for a single layer organic device fabricated by a spin-coating process. A maximum external quantum efficiency (EQE) was 8.9 % at -20 MV/m when the ratio of silole-A:F8BT was 75 mol%. The EQE of the reference device with F8BT only was 0.06 %, and the highest EQE was approximately 160 times higher than that of the reference device. In addition, the photoluminescence (PL) quantum efficiency of the silole- A:F8BT neat film was lower than those of silole-A and F8BT neat films. The lower PL quantum efficiency indicates that the photo-induced carriers efficiently dislocate in the organic layer, resulting in the high EQE of organic photoconductive device.