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ビニルシランと白金触媒を用いる新規有機合成反応の開発《マイレビュー》
https://doi.org/10.24561/00014546
https://doi.org/10.24561/00014546ad72c555-561c-410b-abc8-100932ac1421
名前 / ファイル | ライセンス | アクション |
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KY-AA12504266-02-02.pdf (446.6 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2012-03-02 | |||||
タイトル | ||||||
タイトル | ビニルシランと白金触媒を用いる新規有機合成反応の開発《マイレビュー》 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00014546 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Development of new synthetic organic reactions using vinylsilanes and platinum catalysts | |||||
著者 |
三浦, 勝清
× 三浦, 勝清× 木下, 英典 |
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著者 ローマ字 | ||||||
MIURA, Katsukiyo | ||||||
著者 ローマ字 | ||||||
KINOSHITA, Hidenori | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
書誌情報 |
CACS FORUM 巻 2, p. 2-5, 発行日 2011 |
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年月次 | ||||||
2011-12 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学総合研究機構科学分析支援センター | |||||
出版者名(別言語) | ||||||
出版者 | Comprehensive Analysis Center for Science, Saitama University | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Vinylsilanes have frequently been used as carbon nucleophiles for efficient, stereospecific carbon-carbon bond formation. Their reactions occur usually at the position a to silicon. We herein report the Pt(II)-catalyzed nucleophilic addition of vinylsilanes at the b- or g-position leading to vinylation or allylation products, respectively. Under catalysis by PtCl2-2LiI, (Z)-vinylsilanes reacted with aromatic aldehydes at the position b to silicon, affording allyl silyl ethers in good to high yields. Use of MnI2 instead of LiI was effective in the vinylation of aliphatic aldehydes. We also succeeded in the one-pot vinylation of aldehydes with terminal alkynes and Et3SiH, in which PtCl2 successively catalyzed hydrosilylation of alkynes with Et3SiH and vinylation of aldehydes with the vinylsilanes formed. In contrast, under catalysis by PtCl2-2AgSbF6, the reaction of (Z)-vinylsilanes with dimethyl acetals proceeded at the g-position to give homoallylic ethers in good to high yields. When aldehydes and HC(OMe)3 were used instead of dimethyl acetals, the allylation products were obtained directly from aldehydes. | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2012-03-02 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-AA12504266-02-02 |