SUCRA(さくら: Saitama University Cyber Repository of Academic Resources)は、埼玉大学に在籍する研究者の学術雑誌論文、紀要論文、科学研究費補助金成果報告書、学位論文、研究発表プレゼン資料などを登録し、広く世界に発信しています。 埼玉大学に在籍する皆様は、著作物をSUCRAを通じて発信することができます。詳しくは「成果物の登録方法」をご覧ください。
Development of Surface-bubble-modulated liquid chromatography and its application to the investigation of solute distribution at water/hydrophobic interfaces
Graduate School of Science and Engineering, Saitama University
雑誌名
CACS FORUM : 埼玉大学研究機構科学分析支援センター機関誌
巻
8
ページ
6 - 13
発行年
2017
年月次
2017
出版者名
埼玉大学研究機構科学分析支援センター
出版者名(別言語)
Comprehensive Analysis Center for Science, Saitama University
抄録
A new high-performance liquid chromatographic method termed surface-bubble-modulated liquid chromatography (SBMLC), that has a hybrid separation medium incorporated with surface bubbles fixed in nanopores of a hydrophobic material, is presented. The incorporation of a gas phase at the surface of the hydrophobic material in an aqueous solution leads to the formation of the hybrid separation system consisting of the gas phase, hydrophobic moieties, and the interfacial water on the hydrophobic surface. SBMLC provides a novel technique not only for manipulating the separation selectivity of various compounds by pressure but also for elucidating the mechanism of accumulation or retention of solute compounds in aqueous solutions by a hydrophobic material.