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Catalytic hydration of alkynes over bronsted acid sites developed on halide clusters
https://sucra.repo.nii.ac.jp/records/13123
https://sucra.repo.nii.ac.jp/records/13123860b3ac4-92df-40bc-a7ee-775d7d25910b
名前 / ファイル | ライセンス | アクション |
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A1002455.pdf (317.5 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-02-19 | |||||
タイトル | ||||||
タイトル | Catalytic hydration of alkynes over bronsted acid sites developed on halide clusters | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | catalysis by halide cluster | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | tungsten chloride | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | hydration of alkyne to ketone | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Bronsted acid | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Kamiguchi, Satoshi
× Kamiguchi, Satoshi× Takahashi, Ikuko× Kondo, Kunihiko× Nagashima, Sayoko× Kurokawa, Hideki× Miura, Hiroshi× 千原, 貞次 |
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著者 ローマ字 | ||||||
Kamiguchi, Satoshi | ||||||
著者 ローマ字 | ||||||
Takahashi, Ikuko | ||||||
著者 ローマ字 | ||||||
Kondo, Kunihiko | ||||||
著者 ローマ字 | ||||||
Nagashima, Sayoko | ||||||
著者 ローマ字 | ||||||
Kurokawa, Hideki | ||||||
著者 ローマ字 | ||||||
Miura, Hiroshi | ||||||
著者 ローマ字 | ||||||
Chihara, Teiji | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
独立行政法人理化学研究所 | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
The Institute of Physical and Chemical Research (RIKEN) | ||||||
書誌情報 |
JOURNAL OF CLUSTER SCIENCE 巻 18, 号 4, p. 845-853, 発行日 2007 |
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年月次 | ||||||
2007-12 | ||||||
出版者名 | ||||||
出版者 | SPRINGER/PLENUM PUBLISHERS, | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 10407278 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1007/s10876-007-0160-7 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | When a molecular tungsten halide cluster on silica gel, (H3O)(2)[(W6Cl8)Cl-6] center dot 6H(2)O/SiO2, was treated in a nitrogen stream at temperatures above 250 degrees C, Bronsted acidity appeared as the result of formation of a hydroxo ligand. The cluster catalyzed hydration of 1-hexyne to yield 2-hexanone. The catalytic activity increased with increasing temperature, the selectivity for 2-hexanone being 70% in the temperature range 250-400 degrees C. 1-Heptyne, 1-octyne, 1-nonyne, and phenylacetylene were also preferentially hydrated to produce the corresponding ketones. 2-Hexyne provided 2- and 3-hexanones in equal amounts, as happens with Bronsted acid catalysts. Halide clusters of niobium, molybdenum, and tantalum having the same octahedral metal framework were also active catalysts for the reaction. | |||||
注記 | ||||||
内容記述タイプ | Other | |||||
内容記述 | The original publication is available at http://www.springerlink.com/content/l3754l4qj43w6hv5/ | |||||
版 | ||||||
[著者版] | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2008-02-19 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
A1002455 |