WEKO3
アイテム
{"_buckets": {"deposit": "2108fd9e-c567-4e33-a636-8a4721ae1bee"}, "_deposit": {"created_by": 3, "id": "13142", "owners": [3], "pid": {"revision_id": 0, "type": "depid", "value": "13142"}, "status": "published"}, "_oai": {"id": "oai:sucra.repo.nii.ac.jp:00013142", "sets": ["426"]}, "author_link": ["21093", "21095", "21094", "16687", "21096"], "item_119_biblio_info_8": {"attribute_name": "書誌情報", "attribute_value_mlt": [{"bibliographicIssueDates": {"bibliographicIssueDate": "2006", "bibliographicIssueDateType": "Issued"}, "bibliographicIssueNumber": "1", "bibliographicPageEnd": "56", "bibliographicPageStart": "49", "bibliographicVolumeNumber": "29", "bibliographic_titles": [{"bibliographic_title": "Journal of Separation Science"}]}]}, "item_119_date_31": {"attribute_name": "作成日", "attribute_value_mlt": [{"subitem_date_issued_datetime": "2008-03-10", "subitem_date_issued_type": "Created"}]}, "item_119_description_19": {"attribute_name": "抄録", "attribute_value_mlt": [{"subitem_description": "A new on-line redox derivatization technique using double separation columns and one redox derivatization unit was presented for enhancement of separation selectivity of HPLC. This on-line redox derivatization HPLC system consisted of two separation columns and one redox derivatization unit placed between them. The redox reaction proceeds in the derivatization unit so that an analyte compound migrates as its original form in the first column, while as its oxidized or reduced form in the second column. The retention of the analytes is controlled by the lengths of the two separation columns in this system. We adopted a small column packed with porous graphitic carbon (PGC) as a redox derivatization unit and two C-18 silica columns treated with hexadecyltrimethylammonium. chloride as separation columns. The redox activity of PGC and the efficiency of the on-line redox derivatization HPLC system for enhancement of separation selectivity were investigated using EDTA complexes of some metal ions. Original untreated PGC and PGC treated with hydrogen peroxide completely oxidized Co(II)-EDTA and converted it to Co(Ill)-EDTA, while the other metal complexes eluted as their original oxidation states throughout the system. Selective separation and determination of cobalt in a reference copper alloy by the developed method were demonstrated.", "subitem_description_type": "Abstract"}]}, "item_119_description_21": {"attribute_name": "注記", "attribute_value_mlt": [{"subitem_description": "Copyright(c)2006 John Wiley \u0026 Sons Ltd", "subitem_description_type": "Other"}]}, "item_119_description_29": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"subitem_description": "text", "subitem_description_type": "Other"}]}, "item_119_description_30": {"attribute_name": "フォーマット", "attribute_value_mlt": [{"subitem_description": "application/pdf", "subitem_description_type": "Other"}]}, "item_119_publisher_11": {"attribute_name": "出版者名", "attribute_value_mlt": [{"subitem_publisher": "WILEY-V C H VERLAG GMBH"}]}, "item_119_relation_16": {"attribute_name": "DOI", "attribute_value_mlt": [{"subitem_relation_type": "isVersionOf", "subitem_relation_type_id": {"subitem_relation_type_id_text": "info:doi/10.1002/jssc.200500224", "subitem_relation_type_select": "DOI"}}]}, "item_119_relation_7": {"attribute_name": "著者 外部リンク", "attribute_value_mlt": [{"subitem_relation_name": [{"subitem_relation_name_text": "\u0026EMPTY\u0026"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "\u0026EMPTY\u0026", "subitem_relation_type_select": "URI"}}, {"subitem_relation_name": [{"subitem_relation_name_text": "\u0026EMPTY\u0026"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "\u0026EMPTY\u0026", "subitem_relation_type_select": "URI"}}, {"subitem_relation_name": [{"subitem_relation_name_text": "\u0026EMPTY\u0026"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "\u0026EMPTY\u0026", "subitem_relation_type_select": "URI"}}, {"subitem_relation_name": [{"subitem_relation_name_text": "\u0026EMPTY\u0026"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "\u0026EMPTY\u0026", "subitem_relation_type_select": "URI"}}, {"subitem_relation_name": [{"subitem_relation_name_text": "http://s-read.saitama-u.ac.jp/researchers/pages/researcher/BNzSFxBV"}], "subitem_relation_type_id": {"subitem_relation_type_id_text": "http://s-read.saitama-u.ac.jp/researchers/pages/researcher/BNzSFxBV", "subitem_relation_type_select": "URI"}}]}, "item_119_source_id_14": {"attribute_name": "ISSN", "attribute_value_mlt": [{"subitem_source_identifier": "16159306", "subitem_source_identifier_type": "ISSN"}]}, "item_119_text_27": {"attribute_name": "版", "attribute_value_mlt": [{"subitem_text_value": "[著者版]"}]}, "item_119_text_3": {"attribute_name": "著者 ローマ字", "attribute_value_mlt": [{"subitem_text_value": "Saitoh, Kazunori"}, {"subitem_text_value": "Yamada, Noriko"}, {"subitem_text_value": "Ishikawa, Eri"}, {"subitem_text_value": "Nakajima, Hizuru"}, {"subitem_text_value": "Shibukawa, Masami"}]}, "item_119_text_32": {"attribute_name": "アイテムID", "attribute_value_mlt": [{"subitem_text_value": "A1002474"}]}, "item_119_text_35": {"attribute_name": "公開日(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "Mar 10, 2008 09:00:00"}]}, "item_119_text_36": {"attribute_name": "最終更新日(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "Sep 7, 2009 15:27:19"}]}, "item_119_text_37": {"attribute_name": "更新履歴(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "Sep 7, 2009 フリーキーワード, 著者 を変更"}, {"subitem_text_value": "Mar 17, 2009 フリーキーワード, キーワード を変更"}, {"subitem_text_value": "Mar 11, 2008 フリーキーワード, インデックス, キーワード を変更"}, {"subitem_text_value": "Mar 10, 2008 ID, フリーキーワード, インデックス, 版, キーワード を変更"}]}, "item_119_text_38": {"attribute_name": "登録者(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "sucra_jim4"}]}, "item_119_text_39": {"attribute_name": "閲覧数(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "1500"}]}, "item_119_text_4": {"attribute_name": "著者 所属", "attribute_value_mlt": [{"subitem_text_value": "日本大学生産工学部応用分子化学科"}, {"subitem_text_value": "日本大学生産工学部応用分子化学科"}, {"subitem_text_value": "日本大学生産工学部応用分子化学科"}, {"subitem_text_value": "日本大学生産工学部応用分子化学科"}, {"subitem_text_value": "日本大学生産工学部応用分子化学科(現 : 埼玉大学大学院理工学研究科物質科学部分析化学研究室)"}]}, "item_119_text_40": {"attribute_name": "ダウンロード数(XooNIps)", "attribute_value_mlt": [{"subitem_text_value": "407"}]}, "item_119_text_41": {"attribute_name": "XooNIps_インデックス", "attribute_value_mlt": [{"subitem_text_value": "sucra_jim4|Public/埼玉大学/理工学研究科|Public/埼玉大学/理工学研究科/物質科学部門|Public/ジャンル別/学術雑誌論文(海外)|Public/主題別/化学/複合化学/分析化学"}]}, "item_119_text_42": {"attribute_name": "XooNIps_ITEM_KEY", "attribute_value_mlt": [{"subitem_text_value": "2008"}]}, "item_119_text_5": {"attribute_name": "著者 所属(別言語)", "attribute_value_mlt": [{"subitem_text_value": "Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University"}, {"subitem_text_value": "Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University"}, {"subitem_text_value": "Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University"}, {"subitem_text_value": "Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University"}, {"subitem_text_value": "Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University(Present : Graduate School of Science and Engineering, Saitama University)"}]}, "item_119_text_9": {"attribute_name": "年月次", "attribute_value_mlt": [{"subitem_text_value": "2006-1"}]}, "item_119_version_type_28": {"attribute_name": "著者版フラグ", "attribute_value_mlt": [{"subitem_version_resource": "http://purl.org/coar/version/c_ab4af688f83e57aa", "subitem_version_type": "AM"}]}, "item_creator": {"attribute_name": "著者", "attribute_type": "creator", "attribute_value_mlt": [{"creatorNames": [{"creatorName": "Saitoh, Kazunori"}], "nameIdentifiers": [{"nameIdentifier": "21093", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Yamada, Noriko"}], "nameIdentifiers": [{"nameIdentifier": "21094", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Ishikawa, Eri"}], "nameIdentifiers": [{"nameIdentifier": "21095", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "Nakajima, Hizuru"}], "nameIdentifiers": [{"nameIdentifier": "21096", "nameIdentifierScheme": "WEKO"}]}, {"creatorNames": [{"creatorName": "渋川, 雅美"}, {"creatorName": "シブカワ, マサミ", "creatorNameLang": "ja-Kana"}], "nameIdentifiers": [{"nameIdentifier": "16687", "nameIdentifierScheme": "WEKO"}]}]}, "item_files": {"attribute_name": "ファイル情報", "attribute_type": "file", "attribute_value_mlt": [{"accessrole": "open_date", "date": [{"dateType": "Available", "dateValue": "2018-01-24"}], "displaytype": "detail", "download_preview_message": "", "file_order": 0, "filename": "A1002474.pdf", "filesize": [{"value": "835.9 kB"}], "format": "application/pdf", "future_date_message": "", "is_thumbnail": false, "licensetype": "license_free", "mimetype": "application/pdf", "size": 835900.0, "url": {"label": "A1002474.pdf", "url": "https://sucra.repo.nii.ac.jp/record/13142/files/A1002474.pdf"}, "version_id": "25997c3d-69bc-4ba8-9cb7-b736b2955ace"}]}, "item_keyword": {"attribute_name": "キーワード", "attribute_value_mlt": [{"subitem_subject": "copper alloy", "subitem_subject_scheme": "Other"}, {"subitem_subject": "HPLC", "subitem_subject_scheme": "Other"}, {"subitem_subject": "metal complexes", "subitem_subject_scheme": "Other"}, {"subitem_subject": "on-line redox derivatization", "subitem_subject_scheme": "Other"}, {"subitem_subject": "porous graphitic carbon", "subitem_subject_scheme": "Other"}]}, "item_language": {"attribute_name": "言語", "attribute_value_mlt": [{"subitem_language": "eng"}]}, "item_resource_type": {"attribute_name": "資源タイプ", "attribute_value_mlt": [{"resourcetype": "journal article", "resourceuri": "http://purl.org/coar/resource_type/c_6501"}]}, "item_title": "On-line redox derivatization liquid chromatography using double separation columns and one derivatization unit", "item_titles": {"attribute_name": "タイトル", "attribute_value_mlt": [{"subitem_title": "On-line redox derivatization liquid chromatography using double separation columns and one derivatization unit"}]}, "item_type_id": "119", "owner": "3", "path": ["426"], "permalink_uri": "https://sucra.repo.nii.ac.jp/records/13142", "pubdate": {"attribute_name": "公開日", "attribute_value": "2008-03-10"}, "publish_date": "2008-03-10", "publish_status": "0", "recid": "13142", "relation": {}, "relation_version_is_last": true, "title": ["On-line redox derivatization liquid chromatography using double separation columns and one derivatization unit"], "weko_shared_id": 3}
On-line redox derivatization liquid chromatography using double separation columns and one derivatization unit
https://sucra.repo.nii.ac.jp/records/13142
https://sucra.repo.nii.ac.jp/records/13142e0e41961-d989-4566-b13d-2bd024c81949
名前 / ファイル | ライセンス | アクション |
---|---|---|
A1002474.pdf (835.9 kB)
|
|
Item type | 学術雑誌論文 / Journal Article(1) | |||||
---|---|---|---|---|---|---|
公開日 | 2008-03-10 | |||||
タイトル | ||||||
タイトル | On-line redox derivatization liquid chromatography using double separation columns and one derivatization unit | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | copper alloy | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | HPLC | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | metal complexes | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | on-line redox derivatization | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | porous graphitic carbon | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Saitoh, Kazunori
× Saitoh, Kazunori× Yamada, Noriko× Ishikawa, Eri× Nakajima, Hizuru× 渋川, 雅美 |
|||||
著者 ローマ字 | ||||||
Saitoh, Kazunori | ||||||
著者 ローマ字 | ||||||
Yamada, Noriko | ||||||
著者 ローマ字 | ||||||
Ishikawa, Eri | ||||||
著者 ローマ字 | ||||||
Nakajima, Hizuru | ||||||
著者 ローマ字 | ||||||
Shibukawa, Masami | ||||||
著者 所属 | ||||||
日本大学生産工学部応用分子化学科 | ||||||
著者 所属 | ||||||
日本大学生産工学部応用分子化学科 | ||||||
著者 所属 | ||||||
日本大学生産工学部応用分子化学科 | ||||||
著者 所属 | ||||||
日本大学生産工学部応用分子化学科 | ||||||
著者 所属 | ||||||
日本大学生産工学部応用分子化学科(現 : 埼玉大学大学院理工学研究科物質科学部分析化学研究室) | ||||||
著者 所属(別言語) | ||||||
Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University | ||||||
著者 所属(別言語) | ||||||
Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University | ||||||
著者 所属(別言語) | ||||||
Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University | ||||||
著者 所属(別言語) | ||||||
Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University | ||||||
著者 所属(別言語) | ||||||
Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University(Present : Graduate School of Science and Engineering, Saitama University) | ||||||
書誌情報 |
Journal of Separation Science 巻 29, 号 1, p. 49-56, 発行日 2006 |
|||||
年月次 | ||||||
2006-1 | ||||||
出版者名 | ||||||
出版者 | WILEY-V C H VERLAG GMBH | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 16159306 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1002/jssc.200500224 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A new on-line redox derivatization technique using double separation columns and one redox derivatization unit was presented for enhancement of separation selectivity of HPLC. This on-line redox derivatization HPLC system consisted of two separation columns and one redox derivatization unit placed between them. The redox reaction proceeds in the derivatization unit so that an analyte compound migrates as its original form in the first column, while as its oxidized or reduced form in the second column. The retention of the analytes is controlled by the lengths of the two separation columns in this system. We adopted a small column packed with porous graphitic carbon (PGC) as a redox derivatization unit and two C-18 silica columns treated with hexadecyltrimethylammonium. chloride as separation columns. The redox activity of PGC and the efficiency of the on-line redox derivatization HPLC system for enhancement of separation selectivity were investigated using EDTA complexes of some metal ions. Original untreated PGC and PGC treated with hydrogen peroxide completely oxidized Co(II)-EDTA and converted it to Co(Ill)-EDTA, while the other metal complexes eluted as their original oxidation states throughout the system. Selective separation and determination of cobalt in a reference copper alloy by the developed method were demonstrated. | |||||
注記 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Copyright(c)2006 John Wiley & Sons Ltd | |||||
版 | ||||||
[著者版] | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2008-03-10 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
A1002474 |