WEKO3
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ランタン-アリザリンコンプレクソン-フッ素三元錯体の薄層クロマトグラフィー挙動
https://sucra.repo.nii.ac.jp/records/13152
https://sucra.repo.nii.ac.jp/records/1315237869a4c-f5f9-48fe-bedd-3a694b06757b
名前 / ファイル | ライセンス | アクション |
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A1002495.pdf (281.2 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-03-12 | |||||
タイトル | ||||||
タイトル | ランタン-アリザリンコンプレクソン-フッ素三元錯体の薄層クロマトグラフィー挙動 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | fluoride ion | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | alizarin complexone | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | lanthanum | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | C_18-bonded silica | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | thin layer chromatography | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
タイトル(別言語) | ||||||
その他のタイトル | Thin layer chromatographic behavior of a lanthanum-alizarin complexone-fluoride ternary complex | |||||
著者 |
荒坂, 真吾
× 荒坂, 真吾× 金子, 恵美子× 齋藤, 伸吾× 星, 座× 赤塚, 邦彦 |
|||||
著者 ローマ字 | ||||||
ARASAKA, Shingo | ||||||
著者 ローマ字 | ||||||
KANEKO, Emiko | ||||||
著者 ローマ字 | ||||||
SAITO, Shingo | ||||||
著者 ローマ字 | ||||||
HOSHI, Suwaru | ||||||
著者 ローマ字 | ||||||
AKATSUKA, Kunihiko | ||||||
著者 所属 | ||||||
北見工業大学大学院工学研究科 | ||||||
著者 所属 | ||||||
北見工業大学工学部 | ||||||
著者 所属 | ||||||
北見工業大学工学部 | ||||||
著者 所属 | ||||||
北見工業大学大学院工学研究科 | ||||||
著者 所属 | ||||||
北見工業大学大学院工学研究科 | ||||||
著者 所属(別言語) | ||||||
Department of Applied and Environmental Chemistry, Kitami Institute of Technology | ||||||
著者 所属(別言語) | ||||||
Department of Applied and Environmental Chemistry, Kitami Institute of Technology | ||||||
著者 所属(別言語) | ||||||
Department of Applied and Environmental Chemistry, Kitami Institute of Technology | ||||||
著者 所属(別言語) | ||||||
Department of Applied and Environmental Chemistry, Kitami Institute of Technology | ||||||
著者 所属(別言語) | ||||||
Department of Applied and Environmental Chemistry, Kitami Institute of Technology | ||||||
書誌情報 |
分析化学 巻 51, 号 9, p. 837-839, 発行日 2002 |
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年月次 | ||||||
2002-9 | ||||||
出版者名 | ||||||
出版者 | 社団法人日本分析化学会 | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 05251931 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The thin-layer chromatographic behavior of a lanthanum-alizarin complexone (ALC)-fluoride complex was investigated with particular interest being paid to the separation of the ternary complex from La-ALC. Although the spectral shift of the La-ALC chelate upon binding to the fluoride ion is widely used for the spectrophotometric determination of fluoride ion, there do not appear to be any reports on thin-layer chromatography (TLC) for the ternary complex (La-ALC-F). In this study, it was found that when developed with 60% ethanol on a C_18-bonded silica thin-layer plate, the ternary complex was easily eluted, forming a sharp band. Conversely, the La-ALC chelate was immobilized at the spotting position as a fleck. Furthermore, when a bluish-purple band was separated from a reddish-purple fleck, the ternary complex faded in a few minutes, whereas, when the band remained inside the fleck, no fading took place. These results are interpreted in terms of the dissociation of the labile complex caused by separation from the excess reagent. Consequently, the concentration of the La-ALC-F band across the center of the fleck provides a sensitive visualization of the fluoride ion down to 0.1 ppm. | |||||
その他の言語 | ||||||
言語 | eng | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2008-03-11 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
A1002495 |