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Rearrangement of a (dithiolato)platinum(II) complex formed by reaction of cyclic disulfide 7,8-dithiabicyclo[4.2.1]nona-2,4-diene with a platinum(0) complex: Oxidation of the rearranged (dithiolato)platinum(II) complex
https://sucra.repo.nii.ac.jp/records/13258
https://sucra.repo.nii.ac.jp/records/132584c385fa5-d692-4b25-b63e-21aaeb60ef47
名前 / ファイル | ライセンス | アクション |
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A1002639.pdf (915.3 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-05-15 | |||||
タイトル | ||||||
タイトル | Rearrangement of a (dithiolato)platinum(II) complex formed by reaction of cyclic disulfide 7,8-dithiabicyclo[4.2.1]nona-2,4-diene with a platinum(0) complex: Oxidation of the rearranged (dithiolato)platinum(II) complex | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | platinum | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | X-ray diffraction | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | density functional calculations | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | disulfides | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | oxidation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | rearrangement | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
石井, 昭彦
× 石井, 昭彦 |
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著者 ローマ字 | ||||||
Ishii, Akihiko | ||||||
著者 ローマ字 | ||||||
Kashiura, Satoshi | ||||||
著者 ローマ字 | ||||||
Hayashi, Yuichi | ||||||
著者 ローマ字 | ||||||
Weigand, Wolfgang | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属(別言語) | ||||||
Department of Chemistry, Graduate School of Science and Engineering, Saitama University | ||||||
書誌情報 |
CHEMISTRY-A EUROPEAN JOURNAL 巻 13, 号 15, p. 4326-4333, 発行日 2007 |
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年月次 | ||||||
2007 | ||||||
出版者名 | ||||||
出版者 | WILEY-VCH Verlag GmbH & Co. KGaA | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 09476539 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1002/chem.200601681 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Reaction of the title bicyclic disulfide 16 with [(Ph3P)(2)Pt(eta(2)-C2H4)] (2) yielded the corresponding (dithiolato)platinum(II) complex 17 by oxidative addition. The initial product 17 isomerized at room temperature in a [1,5]-sulfur rearrangement to give another (dithiolato)platinum(II) complex 18 in high isolated yield. Oxidation reactions of 18 with dimethyldioxirane (DMD) provided (sulfenato-thiolato)platinum(II) 23, (sulfinato-thiolato)platinum(II) 24, (sulfenato-sulfinato)platinum(II) 25, and (disulfinato)platinum(II) 26 complexes, the structures of which were elucidated by NMR spectroscopy and X-ray crystallography. The oxidation process took place regioselectively in the first step and chemoselectively in the second. The selectivities are discussed. | |||||
版 | ||||||
[著者版] | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2008-05-14 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
A1002639 |