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Heterogeneous catalysts immobilizing alpha-diimine nickel complexes into fluorotetrasilicic mica interlayers to prepare branched polyethylene from only ethylene
https://sucra.repo.nii.ac.jp/records/13369
https://sucra.repo.nii.ac.jp/records/133696d1b0ffe-75b5-47d9-b36a-462a42817e12
名前 / ファイル | ライセンス | アクション |
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A1002814.pdf (688.4 kB)
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2008-12-26 | |||||
タイトル | ||||||
タイトル | Heterogeneous catalysts immobilizing alpha-diimine nickel complexes into fluorotetrasilicic mica interlayers to prepare branched polyethylene from only ethylene | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Intercalation | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Ion-exchange | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Layered clay minerals | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | journal article | |||||
著者 |
Fuji, Kenji
× Fuji, Kenji× Ishihama, Yoshiyuki× Sakuragi, Tsutomu× Ohshima, Masa-aki× 黒川, 秀樹× 三浦, 弘 |
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著者 ローマ字 | ||||||
Fuji, Kenji | ||||||
著者 ローマ字 | ||||||
Ishihama, Yoshiyuki | ||||||
著者 ローマ字 | ||||||
Sakuragi, Tsutomu | ||||||
著者 ローマ字 | ||||||
Ohshima, Masa-aki | ||||||
著者 ローマ字 | ||||||
Kurokawa, Hideki | ||||||
著者 ローマ字 | ||||||
Miura, Hiroshi | ||||||
著者 所属 | ||||||
埼玉大学理工学研究科物質基礎部門 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
埼玉大学理工学研究科物質基礎部門 | ||||||
著者 所属 | ||||||
埼玉大学理工学研究科物質基礎部門 | ||||||
著者 所属 | ||||||
埼玉大学理工学研究科物質基礎部門 | ||||||
著者 所属 | ||||||
埼玉大学理工学研究科物質基礎部門 | ||||||
著者 所属(別言語) | ||||||
Division of Material Science, Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Polyolefin Technology Center, Japan Polychem Corporation | ||||||
著者 所属(別言語) | ||||||
Division of Material Science, Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Division of Material Science, Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Division of Material Science, Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Division of Material Science, Graduate School of Science and Engineering, Saitama University | ||||||
書誌情報 |
CATALYSIS COMMUNICATIONS 巻 10, 号 2, p. 183-186, 発行日 2008 |
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年月次 | ||||||
2008-11 | ||||||
出版者名 | ||||||
出版者 | ELSEVIER SCIENCE BV | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 15667367 | |||||
DOI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1016/j.catcom.2008.08.015 | |||||
関連サイト | ||||||
内容記述タイプ | Other | |||||
内容記述 | http://www.sciencedirect.com/science/journal/15667367 | http://www.sciencedirect.com/science/journal/15667367 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The alpha-diimine nickel (II) complexes immobilized into the clay mineral interlayer were prepared by the reaction of the Ni2+ ion-exchanged fluorotetrasilicic mica and the alpha-diimine ligand. These procatalysts showed a high catalytic activity for the Slurry, polymerization of ethylene in the presence of methylalumoxane, triethylaluminum or triisobutylaluminum. The activity was strongly affected by the solvent used in the preparation and the steric bulk of the ligand. A high activity (2313 kg-PE mol-Ni-1 h(-1)) was obtained by the polymerization at 50 degrees C in the presence of triisobutylaluminum Using the procatalyst prepared with the [Ar-N = C(CH3)C(CH3)= N-Ar (At = 2,6-C6H3(CH3)(2))] ligand in acetonitrile. (C) 2008 Elsevier B.V. All rights reserved. | |||||
版 | ||||||
[著者版] | ||||||
著者版フラグ | ||||||
出版タイプ | AM | |||||
出版タイプResource | http://purl.org/coar/version/c_ab4af688f83e57aa | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2008-12-26 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
A1002814 |