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ブタジエン合成のための白金系脱水素触媒の開発《マイレビュー》
https://doi.org/10.24561/00014575
https://doi.org/10.24561/000145758d475e6b-b911-4118-b4e2-0d4c8393983f
名前 / ファイル | ライセンス | アクション |
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KY-AA12504266-03-02.pdf (352.9 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2013-03-08 | |||||
タイトル | ||||||
タイトル | ブタジエン合成のための白金系脱水素触媒の開発《マイレビュー》 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00014575 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Development of Pt-based dehydrogenation catalysts used for the synthesis of butadiene | |||||
著者 |
三浦, 弘
× 三浦, 弘 |
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著者 ローマ字 | ||||||
MIURA, Hiroshi | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
書誌情報 |
CACS FORUM 巻 3, p. 2-5, 発行日 2012 |
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年月次 | ||||||
2012-12 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学研究機構科学分析支援センター | |||||
出版者名(別言語) | ||||||
出版者 | Comprehensive Analysis Center for Science, Saitama University | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Dehydrogenation of n-butane was tried over Pt-Sn catalysts supported on various oxides. In contrast to dehydrogenation of propane and isobutane, catalysts supported on ZnAl2O4 and Fe2O3-Al2O3 suggested lower activity than alumina supported catalyst. Instead, Pt-Sn supported on MgO-Al2O3 suggested excellent activity. At higher temperatures, addition of excess amounts of Sn was effective to keep the activity for long time, without deactivation. However, larger amount of Sn addition caused loss of Sn during the preparation process, because volatile SnCl4 was formed. We tried alternative method of preparation. We tried to prepare binary oxide SnO2-Al2O3 by sol-gel method, and then Pt alone was supported by impregnation method. In this case, formation of SnCl4 was avoided and loss of Sn in preparation procedure was negligible. The Pt/SnO2-Al2O3 catalyst prepared in this manner suggested excellent activity for n-butane dehydrogenation. | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2013-03-07 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-AA12504266-03-02 |