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ジフェロセニルチオフェン誘導体の合成とその電気化学的性質<ミニノート>
https://doi.org/10.24561/00014782
https://doi.org/10.24561/000147825104bff5-a302-4b7f-8589-9474050c62c2
名前 / ファイル | ライセンス | アクション |
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KY-AN10402595-13-08.pdf (149.4 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2009-11-12 | |||||
タイトル | ||||||
タイトル | ジフェロセニルチオフェン誘導体の合成とその電気化学的性質<ミニノート> | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00014782 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Synthesis and Electrochemical Properties of Direrrocenyl Thiophenes | |||||
著者 |
佐藤, 勝
× 佐藤, 勝× 白男川, 恵 |
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著者 ローマ字 | ||||||
SATO, Masaru | ||||||
著者 ローマ字 | ||||||
SHIRAOGAWA, Megumi | ||||||
著者 所属 | ||||||
埼玉大学分析センター | ||||||
著者 所属(別言語) | ||||||
Chemical Analysis Center, Saitama University | ||||||
書誌情報 |
CACS FORUM 巻 13, p. 30-32, 発行日 1993 |
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年月次 | ||||||
1993-12 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学分析センター | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Chloroacetylferrocene reacted with sodium sulfide to give bis(ferrocenoylmethyl) sulfide in moderate yield. The reaction of bis(ferrocenoylmethyl)sulfide with the Lawesson reagent gave 2,6-diferrocenyldithiin in high yield, which was led to 2,5-diferrocenyl thiophene by the oxidation with hydrogen peroxide. Bis(ferrocenoylmethyl)sulfide reacted with TiCl4/Zn in refluxing THF and subsequently dehydrogenated by Pd/C to give 3,4-diferrocenylthiophene in moderate yield. The cyclic voltammetry of the thiophene derivatives showed that the 2,5-isomer had larger electron-delocalization in the one electron-oxidized species(the mixed-valence complex) than the 3,4-isomer. | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2010-01-07 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-AN10402595-13-08 |