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ケテン化学の革新(歴史的な大きい誤りとその解決)<総説 レビュー>
https://doi.org/10.24561/00014880
https://doi.org/10.24561/0001488080f8ad70-ea14-407b-aa7d-aa2c4ade3755
名前 / ファイル | ライセンス | アクション |
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KY-AN10402595-20-08.pdf (707.0 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2009-11-12 | |||||
タイトル | ||||||
タイトル | ケテン化学の革新(歴史的な大きい誤りとその解決)<総説 レビュー> | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00014880 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Innovation of Ketene Chemistry. Big Faults in Ketene History and the Solutions. | |||||
著者 |
町口, 孝久
× 町口, 孝久 |
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著者 ローマ字 | ||||||
MACHIGUCHI, Takahisa | ||||||
著者 所属 | ||||||
埼玉大学理学部基礎化学科 | ||||||
著者 所属(別言語) | ||||||
Department of Chemistry, Faculty of Science, Saitama University | ||||||
書誌情報 |
CACS FORUM 巻 20, p. 29-40, 発行日 2000 |
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年月次 | ||||||
2000-11 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学分析センター | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Ever since the first discovery of ketene and its cycloaddition by Staudinger in an early year of this century, an explosive number of studies on ketene reaction has been devoted to developing the reaction. Neverthless, ketene cycloaddition has long been an important problem in organic chemistry. The problems include the nonrecognition for dienes (4π system) and facile reactivity of forbidden-[2 + 2] cycloaddition for olefins (2π system) and unpredictability of product structures. It is still hard to predict whether a certain set of reactants will be successful or not. Modest structural alterations sometimes nullify the capacity of the reaction. Recently, the author and his coworkers have discovered that ketene reacts across its C=O bond, not the C=C one. Based on the result, they are solving the remaining problems in the chemistry. This review outlines the long history of ketene chemistry and describes the way of how the problems have been tackled. | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2009-11-20 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-AN10402595-20-08 |