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ケンプ酸を利用した金属イオンおよび光学活性アミン検出剤の開発<総説 レビュー>
https://doi.org/10.24561/00014882
https://doi.org/10.24561/0001488295c0703e-c656-4285-bc73-48c66be97121
名前 / ファイル | ライセンス | アクション |
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KY-AN10402595-20-10.pdf (508.0 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2009-11-12 | |||||
タイトル | ||||||
タイトル | ケンプ酸を利用した金属イオンおよび光学活性アミン検出剤の開発<総説 レビュー> | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00014882 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Development of Sensing Agents from Kemp’s Triacid Derivatives for Metal Ions and Chiral Amines | |||||
著者 |
廣瀬, 卓司
× 廣瀬, 卓司× 内藤, 久美子× 谷口, 佳代子 |
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著者 ローマ字 | ||||||
HIROSE, Takuji | ||||||
著者 ローマ字 | ||||||
NAITO, Kumiko | ||||||
著者 ローマ字 | ||||||
TANIGUCHI, Kayoko | ||||||
著者 所属 | ||||||
埼玉大学工学部応用化学科 | ||||||
著者 所属 | ||||||
埼玉大学工学部応用化学科 | ||||||
著者 所属 | ||||||
埼玉大学工学部応用化学科 | ||||||
著者 所属(別言語) | ||||||
Department of Applied Chemistry, Saitama University | ||||||
著者 所属(別言語) | ||||||
Department of Applied Chemistry, Saitama University | ||||||
著者 所属(別言語) | ||||||
Department of Applied Chemistry, Saitama University | ||||||
書誌情報 |
CACS FORUM 巻 20, p. 58-67, 発行日 2000 |
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年月次 | ||||||
2000-11 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学分析センター | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Sensing agents for metal ions and chiral amines were preprared from the same starting material, Kemp’s triacid. Kemp’s triacid, cis, cis-1,3,5-trimethyl-1,3,5-cyclohexane tricarboxylic acid, has unique characteristics as a scaffold for sensing agents. Namely, three carboxyl groups are pointing in the same direction from a small cyclic stage. Using target specific design, the carboxyl groups were used separately to recognize the target or signal its presence. For inorganic metal ion sensing, one or two carboxyl groups were used as chelating units while the remaining carboxyl groups served as chromophore linkers. As a result, highly sensitive detection of metal ions was observed by color change from yellow to red. For example, the detection limit for Hg2+ was 4.0 x 10-6 mol dm-3 using an imide monoacid and the same detection limit was observed for Gd3+ using amide diacid. For organic amines, two of the carboxyl groups were derivatized with optically active NMR signaling units and the remaining carboxyl group was used to bind the amines. The resulting optically active diamide monoacids were shown to be useful as NMR shift reagents to determine the optical purities of several chiral amines. | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2009-11-20 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-AN10402595-20-10 |