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C_O/Al_2O_3 触媒を用いた(E)-2-ブテナール水素化反応におけるC_oCl_2の助触媒効果<論文>
https://doi.org/10.24561/00016112
https://doi.org/10.24561/000161122766c15c-3479-472c-9867-a3498e7bcc53
名前 / ファイル | ライセンス | アクション |
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KY-AN00095842-39-09.pdf (720.1 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2008-03-19 | |||||
タイトル | ||||||
タイトル | C_O/Al_2O_3 触媒を用いた(E)-2-ブテナール水素化反応におけるC_oCl_2の助触媒効果<論文> | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00016112 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Promoting Effect of C_oCl_2 on the Hydrogenation of (E)-2-butenal over Co/Al_2O_3 Catalysts | |||||
著者 |
塚越, 康之
× 塚越, 康之× 森, 健治× 大友, 昭典× 大嶋, 正明× 黒川, 秀樹× 杉山, 和夫× 三浦, 弘 |
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著者 ローマ字 | ||||||
TSUKAGOSHI, Yasuyuki | ||||||
著者 ローマ字 | ||||||
MORI, Kenji | ||||||
著者 ローマ字 | ||||||
OHTOMO, Akinori | ||||||
著者 ローマ字 | ||||||
OHSHIMA, Masaaki | ||||||
著者 ローマ字 | ||||||
KUROKAWA, Hideki | ||||||
著者 ローマ字 | ||||||
SUGIYAMA, Kazuo | ||||||
著者 ローマ字 | ||||||
MIURA, Hiroshi | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
書誌情報 |
埼玉大学紀要. 工学部 第1編 第1部 論文集 en : The Science and Engineering Reports of Saitama University 巻 39, p. 54-57, 発行日 2006 |
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年月次 | ||||||
2006-7 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学工学部 | |||||
出版者名(別言語) | ||||||
出版者 | Faculty of Engineering, Saitama University | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 18804446 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Selective hydrogenation of the C=O bond of α,β-unsaturated aldehyde to form unsaturated alcohol was tried in liquid phase over C_O/Al_2O_3 catalysts. When C_O/Al_2O_3 was prepared from C_O(NO3)2, and Cl-free, activity and selectivity to form unsaturated alcohol was low. Addition of C_OCl_2 in the reaction mixture promoted the selective hydrogenation remarkably. Concentration of Cl in the liquid phase was determined, as well as the amount of adsorbed Cl. A clear relation was found between the C=O hydrogenation activity and the amount of adsorbed Cl. When C_O/Al_2O_3 was prepared from C_oCl_2, Cl remained in the catalyst even after reduction treatment. This catalyst suggested both high activity and selectivity toward unsaturated alcohol formation. The role of chloride ion, existing on the catalyst surface, in selective hydrogenation was discussed. | |||||
その他の言語 | ||||||
言語 | eng | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2008-03-19 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-AN00095842-39-09 |