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3-メチレン-2,3-ジヒドロセレノフェン誘導体の合成と蛍光特性
https://doi.org/10.24561/00016516
https://doi.org/10.24561/000165161d954959-32d4-4e95-bf1d-f6321865c874
名前 / ファイル | ライセンス | アクション |
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KY-18838278-2-13.pdf (178.6 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2010-07-30 | |||||
タイトル | ||||||
タイトル | 3-メチレン-2,3-ジヒドロセレノフェン誘導体の合成と蛍光特性 | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Selenium | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Fluorescence | |||||
キーワード | ||||||
主題Scheme | Other | |||||
主題 | Functionalization | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00016516 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Synthesis and Fluorescence Properties of 3-Methylene-2,3-dihydroselenophene Derivatives | |||||
著者 |
中田, 憲男
× 中田, 憲男× 山口, 雄規× 石井, 昭彦 |
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著者 ローマ字 | ||||||
NAKATA, Norio | ||||||
著者 ローマ字 | ||||||
YAMAGUCHI, Yuki | ||||||
著者 ローマ字 | ||||||
ISII, Akihiko | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科 | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科 | ||||||
著者 所属(別言語) | ||||||
Department of Chemistry, Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Department of Chemistry, Graduate School of Science and Engineering, Saitama University | ||||||
著者 所属(別言語) | ||||||
Department of Chemistry, Graduate School of Science and Engineering, Saitama Un | ||||||
書誌情報 |
埼玉大学地域オープンイノベーションセンター紀要 en : Report of Comprehensive Open Innovation Center, Saitama University 巻 2, p. 31-31, 発行日 2010 |
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年月次 | ||||||
2010-7 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学総合研究機構地域オープンイノベーションセンター | |||||
ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 18838278 | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | We found that 3-methylene-2,3- dihydroselenophene derivative 1 was synthesized by the thermal reaction of the corresponding selenaplatinacycle with DMAD. The UV/vis spectrum of 1 in CH2Cl2 showed the longest absorption maxima at 370 nm, which is attributable to the HOMO-LUMO transition of the 3-methylene-2,3-dihydroselenophene part. In the fluorescence spectrum, 1 exhibited an intense emission at 494 nm with the quantum yield (ΦF) of 0.66. We also examined functionalization of methoxy carbonyl groups of 1. Thus, diester 1 was readily hydrolyzed in aq. NaOH to give the corresponding dicarboxylic acid 2 in 86% yield. In addition, refluxing a solution of 2 in Ac2O provided the corresponding acid anhydride derivative 3 in 72% yield. In fluorescence spectra of 2 and 3, the emission maxima were observed at 507 and 517 nm, respectively, which are red-shifted compared with 1. |
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版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2010-07-30 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-18838278-2-13 |