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リン酸配位子が形成する配位高分子における非通常系列のランタノイドイオン交換特性《若手研究者の紹介》
https://doi.org/10.24561/00018820
https://doi.org/10.24561/0001882067db65d2-0979-4d04-a8b8-654408242b4c
名前 / ファイル | ライセンス | アクション |
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KY-AA12504266-10-05.pdf (571.4 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2020-02-13 | |||||
タイトル | ||||||
タイトル | リン酸配位子が形成する配位高分子における非通常系列のランタノイドイオン交換特性《若手研究者の紹介》 | |||||
言語 | ||||||
言語 | jpn | |||||
資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||
資源タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.24561/00018820 | |||||
ID登録タイプ | JaLC | |||||
タイトル(別言語) | ||||||
その他のタイトル | Unusual lanthanide ion exchange series of coordination polymers based on phosphorous ligand | |||||
著者 |
半田, 友衣子
× 半田, 友衣子 |
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著者 ローマ字 | ||||||
HANDA, Yuiko | ||||||
著者 所属 | ||||||
埼玉大学大学院理工学研究科物質科学部門 | ||||||
著者 所属(別言語) | ||||||
Graduate School of Science and Engineering, Saitama University | ||||||
書誌情報 |
CACS FORUM : 埼玉大学研究機構科学分析支援センター機関誌 巻 10, p. 30-33, 発行日 2019 |
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年月次 | ||||||
2019 | ||||||
出版者名 | ||||||
出版者 | 埼玉大学研究機構科学分析支援センター | |||||
出版者名(別言語) | ||||||
出版者 | Comprehensive Analysis Center for Science, Saitama University | |||||
概要 | ||||||
内容記述タイプ | Other | |||||
内容記述 | Recognition and separation of individual lanthanide(III) ions (Ln3+) are rather difficult and remain a challenging task because of their similar properties. In this report, Ln3+ exchange in coordination polymers (CPs) and exceptional ion-exchange selectivity offered by restricted coordination sites in the CPs are discussed. Di(2-ethylhexyl) phosphoric acid (Hdehp), which is effective for Ln3+ mutual separation, was employed as a linkage (L) and [LnL3] was synthesized. Partial exchange of central Ln3+ by the other kind of Ln3+ and an unique affinity having a maximum in the Ln series is shown: Ln3+ selectivity, in general, monotonously varies in the series. The affinity sequence depends on an ionic radius of central Ln3+, indicating that not only coordination ability between Ln3+ and the linkage but also difference in ionic size between an original and an incoming Ln3+ are significant to ion-exchange selectivity. | |||||
版 | ||||||
[出版社版] | ||||||
著者版フラグ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
資源タイプ | ||||||
内容記述タイプ | Other | |||||
内容記述 | text | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
作成日 | ||||||
日付 | 2020-02-12 | |||||
日付タイプ | Created | |||||
アイテムID | ||||||
KY-AA12504266-10-05 |