@phdthesis{oai:sucra.repo.nii.ac.jp:00010355,
 author = {安中, 辰朗},
 month = {},
 note = {119 p., Chapter 1 General Introduction……………………………………………………7
1-1 Introduction……………………………………………………………………8
1-2 Fluorescent Compounds Containing Heteroatom………………………………9
1-3 Organochalcogen Compounds………………………………………………11
1-4 Heavy-atom Effect………………………………………………………………12
1-5 Chalcogenaplatinacycles and 1-Chalcogeno-1,3-butadienes……………………14
1-6 Studies in the Master Thesis……………………………………………………16
　1-6-1 Fluorescent 1-Thio- and 1-Seleno-1,3-butadienes Synthesized via an
Intramolecular Cycloaddition
　1-6-2 Developed Intramolecular Cycloaddition
1-7 This Work………………………………………………………………………20
1-8 Reference………………………………………………………………………22

Chapter 2 Syntheses, Structures, and Photophysical Properties of Extended π-Conjugative and Push-pull Type 1,4-Diaryl-1-thio-1,3-butadienes………………29
2-1 Introduction……………………………………………………………………30
2-2 Syntheses and Structures of Push-pull Type 1-Thio-1,3-butadienes……………32
2-3 Properties of Push-pull Type 1-Thio-1,3-butadienes…………………………35
2-4 Conclusion……………………………………………………………………41
2-5 Experimental Section…………………………………………………………42
2-6 Reference…………………………………………………………………46

Chapter 3 Synthesis, Structures, Photophysical Properties, and Derivations of 1,4-Diphenyl-1-telluro-1,3-butadienes……………………………………………51
3-1 Introduction…………………………………………………………………52
3-2 Syntheses and Structures of 1,4-Dipheny-1-telluro-1,3-butadienes……………55
3-3 Silylations of 1,4-Diphenyl-1-telluro-1,3-butadienes………………………62
3-4 Photophysical Properties of 1,4-Diphenyl-1-telluro-1,3-butadienes…………63
3-5 Conclusion……………………………………………………………………69
3-6 Experimental Section…………………………………………………………70
3-7 Reference……………………………………………………………………74

Chapter 4 Reversible and Turn-on Fluorescent Probes for Hydrogen Sulfide via redox cycle between Selenide and Selenoxide………………………………………81
4-1 Introduction…………………………………………………………………82
4-2 Syntheses and Structures of 1,4-Diphenyl-1-seleno-1,3-butadiene 1-Oxides…86
4-3 Photophysical Properties of 1,4-Diphenyl-1-seleno-1,3-butadienes…………91
4-4 Sensing Abilities………………………………………………………………95
4-5 Conclusion……………………………………………………………………103
4-6 Experimental Section…………………………………………………………104
4-7 Reference……………………………………………………………………107

Chapter 5 Conclusion and Outlook……………………………………………113

Acknowledgments……………………………………………………………117
List of Publications………………………………………………………………119, text, application/pdf},
 school = {埼玉大学},
 title = {Luminescent 1-Chalcogeno-1,3-butadiene : Elucidation of Photophysical Properties and Application to Hydrogen Sulfide Sensor},
 year = {2015},
 yomi = {アンナカ, タツロウ}
}