{"created":"2023-05-15T15:23:30.644052+00:00","id":10355,"links":{},"metadata":{"_buckets":{"deposit":"fbece8c6-ecae-467d-82b0-2d769994e20d"},"_deposit":{"created_by":15,"id":"10355","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"10355"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00010355","sets":["94:429:431:432:506"]},"author_link":[],"item_113_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"発光性1- カルコゲノ-1,3- ブタジエン : 光物性の解明と硫化水素蛍光センサーへの応用"}]},"item_113_biblio_info_9":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2015","bibliographicIssueDateType":"Issued"}}]},"item_113_date_35":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2015-12-16","subitem_date_issued_type":"Created"}]},"item_113_date_granted_20":{"attribute_name":"学位授与年月日","attribute_value_mlt":[{"subitem_dategranted":"2015-03-24"}]},"item_113_degree_grantor_22":{"attribute_name":"学位授与機関","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_name":"埼玉大学"}],"subitem_degreegrantor_identifier":[{"subitem_degreegrantor_identifier_name":"12401","subitem_degreegrantor_identifier_scheme":"kakenhi"}]}]},"item_113_degree_name_21":{"attribute_name":"学位名","attribute_value_mlt":[{"subitem_degreename":"博士(理学)"}]},"item_113_description_13":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_description":"119 p.","subitem_description_type":"Other"}]},"item_113_description_24":{"attribute_name":"目次","attribute_value_mlt":[{"subitem_description":"Chapter 1 General Introduction……………………………………………………7\n1-1 Introduction……………………………………………………………………8\n1-2 Fluorescent Compounds Containing Heteroatom………………………………9\n1-3 Organochalcogen Compounds………………………………………………11\n1-4 Heavy-atom Effect………………………………………………………………12\n1-5 Chalcogenaplatinacycles and 1-Chalcogeno-1,3-butadienes……………………14\n1-6 Studies in the Master Thesis……………………………………………………16\n　1-6-1 Fluorescent 1-Thio- and 1-Seleno-1,3-butadienes Synthesized via an\nIntramolecular Cycloaddition\n　1-6-2 Developed Intramolecular Cycloaddition\n1-7 This Work………………………………………………………………………20\n1-8 Reference………………………………………………………………………22\n\nChapter 2 Syntheses, Structures, and Photophysical Properties of Extended π-Conjugative and Push-pull Type 1,4-Diaryl-1-thio-1,3-butadienes………………29\n2-1 Introduction……………………………………………………………………30\n2-2 Syntheses and Structures of Push-pull Type 1-Thio-1,3-butadienes……………32\n2-3 Properties of Push-pull Type 1-Thio-1,3-butadienes…………………………35\n2-4 Conclusion……………………………………………………………………41\n2-5 Experimental Section…………………………………………………………42\n2-6 Reference…………………………………………………………………46\n\nChapter 3 Synthesis, Structures, Photophysical Properties, and Derivations of 1,4-Diphenyl-1-telluro-1,3-butadienes……………………………………………51\n3-1 Introduction…………………………………………………………………52\n3-2 Syntheses and Structures of 1,4-Dipheny-1-telluro-1,3-butadienes……………55\n3-3 Silylations of 1,4-Diphenyl-1-telluro-1,3-butadienes………………………62\n3-4 Photophysical Properties of 1,4-Diphenyl-1-telluro-1,3-butadienes…………63\n3-5 Conclusion……………………………………………………………………69\n3-6 Experimental Section…………………………………………………………70\n3-7 Reference……………………………………………………………………74\n\nChapter 4 Reversible and Turn-on Fluorescent Probes for Hydrogen Sulfide via redox cycle between Selenide and Selenoxide………………………………………81\n4-1 Introduction…………………………………………………………………82\n4-2 Syntheses and Structures of 1,4-Diphenyl-1-seleno-1,3-butadiene 1-Oxides…86\n4-3 Photophysical Properties of 1,4-Diphenyl-1-seleno-1,3-butadienes…………91\n4-4 Sensing Abilities………………………………………………………………95\n4-5 Conclusion……………………………………………………………………103\n4-6 Experimental Section…………………………………………………………104\n4-7 Reference……………………………………………………………………107\n\nChapter 5 Conclusion and Outlook……………………………………………113\n\nAcknowledgments……………………………………………………………117\nList of Publications………………………………………………………………119","subitem_description_type":"Other"}]},"item_113_description_33":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_113_description_34":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_113_dissertation_number_19":{"attribute_name":"学位授与番号","attribute_value_mlt":[{"subitem_dissertationnumber":"甲第973号"}]},"item_113_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00010349","subitem_identifier_reg_type":"JaLC"}]},"item_113_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学大学院理工学研究科"}]},"item_113_publisher_12":{"attribute_name":"出版者名（別言語）","attribute_value_mlt":[{"subitem_publisher":"Graduate School of Science and Engineering, Saitama 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Sensor","subitem_title_language":"en"}]},"item_type_id":"113","owner":"15","path":["506"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2015-12-17"},"publish_date":"2015-12-17","publish_status":"0","recid":"10355","relation_version_is_last":true,"title":["Luminescent 1-Chalcogeno-1,3-butadiene : Elucidation of Photophysical Properties and Application to Hydrogen Sulfide Sensor"],"weko_creator_id":"15","weko_shared_id":-1},"updated":"2023-06-23T04:29:22.615910+00:00"}