@article{oai:sucra.repo.nii.ac.jp:00012487, author = {松岡, 浩司 and 照沼, 大陽 and 幡野, 健}, issue = {18}, journal = {Tetrahedron letters}, month = {}, note = {http://www.sciencedirect.com/science/journal/00404039 | http://www.sciencedirect.com/science/journal/00404039, A novel anomeric b-thioacetate of an N-acetyllactosamine derivative was efficiently synthesized in high yield from the known 2-azido glycosyl chloride using thioacetic acid as a convenient reagent. The synthesis involved not only an SN2 replacement of the chloride by a carbothiolate anion but also a reductive acetamidation of the azide group. Applications of the thioacetate for glycosidation were demonstrated to provide both O- and S-glycosides in high yields. Furthermore, both intermediates gave a new class of glycoclusters that included thioglycosidic linkages., text, application/pdf}, title = {Synthesis of a useful anomeric thioacetate of an N-acetyllactosamine derivative and its application}, volume = {44}, year = {2003}, yomi = {マツオカ, コウジ and テルヌマ, ダイヨウ and ハタノ, ケン} }