{"created":"2023-05-15T15:25:01.522396+00:00","id":12488,"links":{},"metadata":{"_buckets":{"deposit":"3a7f6b83-cf45-4a23-b50b-6481e76236ad"},"_deposit":{"created_by":3,"id":"12488","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"12488"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00012488","sets":["94:426"]},"author_link":["16486","19554"],"item_119_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2001","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"19-Jan","bibliographicVolumeNumber":"11-Feb","bibliographic_titles":[{"bibliographic_title":"Tetrahedron letters"}]}]},"item_119_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2007-03-05","subitem_date_issued_type":"Created"}]},"item_119_description_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_description":"http://www.sciencedirect.com/science/journal/00404039 | http://www.sciencedirect.com/science/journal/00404039","subitem_description_type":"Other"}]},"item_119_description_19":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A new approach for the formation of an acetylthio linkage on aglycon by means of a radical addition of thioacetic acid into the C=C double bond of the aglycon was examined.  An introduction of a carbohydrate moiety into carbosilane dendrimers was demonstrated using a one-pot coupling reaction in MeOH¾DMF in the presence of NaOMe via removal of an acetyl group of the acetylthio linkage in the saccharide moieties, producing a thiolate anion and a nucleophilic replacement of the thiolate to dendric alkyl bromide to form carbosilane dendrimers uniformly bearing lactose or sialyllactose moieties through thioether linkages in high yields.","subitem_description_type":"Abstract"}]},"item_119_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_119_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_119_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"Elsevier Science Ltd."}]},"item_119_relation_16":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1016/S0040-4039(01)00422-1","subitem_relation_type_select":"DOI"}}]},"item_119_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00404039","subitem_source_identifier_type":"ISSN"}]},"item_119_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[著者版]"}]},"item_119_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"Matsuoka, Koji"},{"subitem_text_value":"Terunuma, Daiyo"},{"subitem_text_value":"Oka, Hiroyuki"},{"subitem_text_value":"Koyama, Tetsuo"},{"subitem_text_value":"Esumi, Yasuaki"}]},"item_119_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"A1001654"}]},"item_119_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科"},{"subitem_text_value":"埼玉大学大学院理工学研究科"}]},"item_119_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Saitama University, Graduate School of Science and Engineering"},{"subitem_text_value":"Saitama University, Graduate School of Science and Engineering"}]},"item_119_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2001"}]},"item_119_textarea_25":{"attribute_name":"アクセス条件","attribute_value_mlt":[{"subitem_textarea_value":"Private"}]},"item_119_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"松岡, 浩司"},{"creatorName":"マツオカ, コウジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"照沼, 大陽"},{"creatorName":"テルヌマ, ダイヨウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"A1001654.pdf","filesize":[{"value":"35.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"A1001654.pdf","url":"https://sucra.repo.nii.ac.jp/record/12488/files/A1001654.pdf"},"version_id":"75d6a1f6-d185-41a5-b6e5-62c5469568a3"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"radical additions","subitem_subject_scheme":"Other"},{"subitem_subject":"thioacetate","subitem_subject_scheme":"Other"},{"subitem_subject":"carbosilane dendrimers","subitem_subject_scheme":"Other"},{"subitem_subject":"sulfide","subitem_subject_scheme":"Other"},{"subitem_subject":"glycodendrimers","subitem_subject_scheme":"Other"},{"subitem_subject":"Carbohydrates","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"An alternative route for the construction of carbosilane dendrimers uniformly functionalized with lactose or sialyllactose moieties","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"An alternative route for the construction of carbosilane dendrimers uniformly functionalized with lactose or sialyllactose moieties"}]},"item_type_id":"119","owner":"3","path":["426"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-03-08"},"publish_date":"2007-03-08","publish_status":"0","recid":"12488","relation_version_is_last":true,"title":["An alternative route for the construction of carbosilane dendrimers uniformly functionalized with lactose or sialyllactose moieties"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T13:03:23.155295+00:00"}