{"created":"2023-05-15T15:25:02.184001+00:00","id":12503,"links":{},"metadata":{"_buckets":{"deposit":"55d6f7a7-4126-452b-8ba2-7b643860073d"},"_deposit":{"created_by":3,"id":"12503","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"12503"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00012503","sets":["94:426"]},"author_link":["19567","16486","18413"],"item_119_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2004","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"51","bibliographicPageEnd":"9386","bibliographicPageStart":"9383","bibliographicVolumeNumber":"45","bibliographic_titles":[{"bibliographic_title":"Tetrahedron letters"}]}]},"item_119_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2007-03-05","subitem_date_issued_type":"Created"}]},"item_119_description_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_description":"http://www.sciencedirect.com/science/journal/00404039 | http://www.sciencedirect.com/science/journal/00404039","subitem_description_type":"Other"}]},"item_119_description_19":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"An efficient synthesis of a useful thioglycosyl donor 2 was accomplished directly from　known peracetylated sialic acid methyl ester and 1-dodecanethiol (lauryl mercaptan) in the presence of BF3—OEt2. The reactivities of the lauryl glycosides for glycosidation by means of TMSOTf as a convenient promoter were investigated, and　the lauryl thioglycoside showed satisfactory activities. Further transformation of the lauryl glycoside was also attempted to give a 5-azide analogue 14 of the sialic acid, which was also reacted with a secondary alcohol in the presence of TMSOTf to give known glycoside 15 in high yield.","subitem_description_type":"Abstract"}]},"item_119_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_119_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_119_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"Elsevier Science Ltd."}]},"item_119_relation_16":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1016/j.tetlet.2004.10.105","subitem_relation_type_select":"DOI"}}]},"item_119_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00404039","subitem_source_identifier_type":"ISSN"}]},"item_119_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[著者版]"}]},"item_119_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"Matsuoka, Koji"},{"subitem_text_value":"Terunuma, Daiyo"},{"subitem_text_value":"Hatano, Ken"},{"subitem_text_value":"Onaga, Tomotsune"},{"subitem_text_value":"Mori, Tomonori"},{"subitem_text_value":"Sakamoto, Jun-Ichi"},{"subitem_text_value":"Koyama, Tetsuo"},{"subitem_text_value":"Sakairi, Nobuo"}]},"item_119_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"A1000560"}]},"item_119_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科"},{"subitem_text_value":"埼玉大学大学院理工学研究科"},{"subitem_text_value":"埼玉大学大学院理工学研究科"}]},"item_119_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"},{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"},{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"}]},"item_119_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2004-12"}]},"item_119_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"松岡, 浩司"},{"creatorName":"マツオカ, コウジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"照沼, 大陽"},{"creatorName":"テルヌマ, ダイヨウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"幡野, 健"},{"creatorName":"ハタノ, ケン","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"A1000560.pdf","filesize":[{"value":"73.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"A1000560.pdf","url":"https://sucra.repo.nii.ac.jp/record/12503/files/A1000560.pdf"},"version_id":"1be6a63f-6e59-4c36-8302-d944b0e87573"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Thioglycosides","subitem_subject_scheme":"Other"},{"subitem_subject":"Lauryl mercaptan","subitem_subject_scheme":"Other"},{"subitem_subject":"Sialic acid","subitem_subject_scheme":"Other"},{"subitem_subject":"Glycosidation","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of a useful lauryl thioglycoside of sialic acid and its application","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of a useful lauryl thioglycoside of sialic acid and its application"}]},"item_type_id":"119","owner":"3","path":["426"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-03-08"},"publish_date":"2007-03-08","publish_status":"0","recid":"12503","relation_version_is_last":true,"title":["Synthesis of a useful lauryl thioglycoside of sialic acid and its application"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T13:02:42.397128+00:00"}