{"created":"2023-05-15T15:25:03.731996+00:00","id":12540,"links":{},"metadata":{"_buckets":{"deposit":"07b8b84d-77d3-403b-a8f8-9919e96f3680"},"_deposit":{"created_by":3,"id":"12540","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"12540"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00012540","sets":["94:426"]},"author_link":["19597"],"item_119_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"二層式光化学電池の仮想デバイスシミュレータの作成"}]},"item_119_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicVolumeNumber":"8","bibliographic_titles":[{"bibliographic_title":"Journal of Chemical Software"}]}]},"item_119_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2007-03-05","subitem_date_issued_type":"Created"}]},"item_119_description_19":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"A virtual bipolar photogalvanic cell was developed using Visual Basic. On the basis of the simulation, it　is indicated that the charge separation (kd) and the charge recombination (kr) rate constants can be estimated　using the photocurrent response. The thickness of the charge separation region can be anticipated by photocurrentresponse at various layer thicknesses. The increase in diffusion coefficients raises the short-circuit　photocurrent to enhance the performance of the photogalvanic cell. An actual device was fabricated usingtris(bipyridine)ruthenium(II) complex ([Ru(bpy)3　2+]) as a sensitizer and Prussian Blue as a mediator. This device　worked as a photogalvanic cell: short-circuit photocurrent (JSC), 2.3μA/cm2; open-circuit photovoltage　(VOC), 0.118V; fill-factor, 20.5 %. It was shown from the action spectrum that electrons are transferred from　[Ru(bpy)3　2+*] to Prussian Blue. The charge separation and the recombination rate constants were estimated,　using the virtual device, to be 5 _ 102 mol-1cm3s-1 and 6 _ 109 mol-1cm3s-1, respectively.","subitem_description_type":"Abstract"}]},"item_119_description_21":{"attribute_name":"注記","attribute_value_mlt":[{"subitem_description":"Copyright 2002 Society of Computer Chemistry,Japan.This paper was published in \"Sumio. Tokita, J.Comput. Chem. Jpn., 8(2), 47-54, 2002. The internet address of the above Journal is as follows: http://www.sccj.net/","subitem_description_type":"Other"}]},"item_119_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_119_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_119_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"日本コンピュータ化学会"}]},"item_119_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09180761","subitem_source_identifier_type":"ISSN"}]},"item_119_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"Tokita, Sumio"},{"subitem_text_value":"Shiroishi, Hidenobu"},{"subitem_text_value":"Kaburagi, Yuuki"},{"subitem_text_value":"Seo, Michiko"},{"subitem_text_value":"Hoshi, Takayuki"},{"subitem_text_value":"Nomura,Tomoyo"},{"subitem_text_value":"Kaneko, Masao"}]},"item_119_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"A1002095"}]},"item_119_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科"}]},"item_119_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"}]},"item_119_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2002"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"時田, 澄男"},{"creatorName":"トキタ, スミオ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"A1002095.pdf","filesize":[{"value":"180.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"A1002095.pdf","url":"https://sucra.repo.nii.ac.jp/record/12540/files/A1002095.pdf"},"version_id":"693ab635-003a-4c34-b154-3055e6f4538c"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Virtual Device Simulator of Bipolar Photogalvanic Cell","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Virtual Device Simulator of Bipolar Photogalvanic Cell"}]},"item_type_id":"119","owner":"3","path":["426"],"pubdate":{"attribute_name":"公開日","attribute_value":"2007-03-09"},"publish_date":"2007-03-09","publish_status":"0","recid":"12540","relation_version_is_last":true,"title":["Virtual Device Simulator of Bipolar Photogalvanic Cell"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T13:01:14.428383+00:00"}