@article{oai:sucra.repo.nii.ac.jp:00012845, author = {柳瀬, 郁夫 and 小林, 秀彦 and 三田村, 孝}, issue = {1259}, journal = {日本セラミックス協会学術論文誌}, month = {}, note = {http://ci.nii.ac.jp/naid/110002289877/ | http://ci.nii.ac.jp/naid/110002289877/, Cubic Cs_2FeSi_5O_<12> powder with the space group Iα-3d was synthesized by heating the powder mixture of Cs_2CO_3・2H_2O, Fe_3O_4 and amorphous SiO_2 with the molar ratio of Cs/Fe=2 and Si/Fe=5 at 1273 K for 20 h under Ar gas flow. The thermal expansion property of cubic Cs_2FeSi_5O_<12> powder was investigated in the temperature range from 298 to 1273 K using high-temperature X-ray diffraction. The thermal expansion rate of cubic Cs_2FeSi_5O_<12> was lower than that of cubic CsFeSi_2O_6. Consequently, increasing the molar ratio of Si/Fe was effective for decreasing the thermal expansion rate of Cs-Fe-leucite compounds. Cubic Cs_2FeSi_5O_<12> showed a lower thermal expansion with the mean linear thermal expansion coefficient of 1.75×10^<-6>K^<-1> in the range from 573 to 1273 K., rights: 社団法人日本セラミックス協会 rights: 本文データは学協会の許諾に基づきCiNiiから複製したものである relation: isVersionOf: http://ci.nii.ac.jp/naid/110002289877/, text, application/pdf}, pages = {677--680}, title = {Ar雰囲気中での立方晶Cs_2FeSi_5O_<12>粉末の合成とその熱膨張特性}, volume = {108}, year = {2000}, yomi = {ヤナセ, イクオ and コバヤシ, ヒデヒコ and ミタムラ, タカシ} }