{"created":"2023-05-15T15:25:22.306004+00:00","id":12976,"links":{},"metadata":{"_buckets":{"deposit":"866829d5-5339-402c-9787-28cab1d9c412"},"_deposit":{"created_by":3,"id":"12976","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"12976"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00012976","sets":["94:426"]},"author_link":["20622","20626","20623","20624","20625","18337"],"item_119_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Order-Disorder Transition of BaM_2O_4 Bodies (M : La, Nd, Sm, Gd, Ho or Y) Synthesized by Sintering of BaCO_3-M_2O_3 Mixtures"}]},"item_119_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1994","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"1186","bibliographicPageEnd":"586","bibliographicPageStart":"583","bibliographicVolumeNumber":"102","bibliographic_titles":[{"bibliographic_title":"日本セラミックス協会学術論文誌"}]}]},"item_119_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2008-01-09","subitem_date_issued_type":"Created"}]},"item_119_description_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_description":"http://ci.nii.ac.jp/naid/110002290617/ | http://ci.nii.ac.jp/naid/110002290617/","subitem_description_type":"Other"}]},"item_119_description_19":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Sintered bodies of BaM_2O_4 (M : La, Nd, Sm, Gd, Ho or Y) with CaFe_2O_4 related structure were synthesized by sintering BaCO_3 M_2O_3 mixtures. The temperature de pendence of oxygen ionic conductivity and the relation ship between the ionic radius of M^<3+> ions in B sites and the crystal structure of BaM_2O_4 were investigated. The ionic conductivity type in BaM_2O_4 was divided into two groups; (a) BaLa_2O_4, BaNd_2O_4 and BaSm_2O_4 with ord er disorder transition and (b) BaGd_2O_4, BaHO_2O_4 and BaY_2O_4 without the transition. There were vacant spaces in the crystal structure of BaNd_2O_4 and BaSm_2O_4 with order disorder transition due to the dis tortion in the a axis direction of an oxygen octahedron. By assuming that the vacant space is an oxygen vacan cy, the ionic conductivity in BaLa_2O_4, BaNd_2O_4 and BaSln_2O_4 has been explained with a model of the order disorder transition for oxygen vacancies without sig nificant shifting of cations in the crystal lattice.","subitem_description_type":"Abstract"}]},"item_119_description_21":{"attribute_name":"注記","attribute_value_mlt":[{"subitem_description":"rights: 社団法人日本セラミックス協会\nrights: 本文データは学協会の許諾に基づきCiNiiから複製したものである\nrelation: IsVersionOf: http://ci.nii.ac.jp/naid/110002290617/","subitem_description_type":"Other"}]},"item_119_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_119_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_119_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"社団法人日本セラミックス協会"}]},"item_119_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"09145400","subitem_source_identifier_type":"ISSN"}]},"item_119_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_119_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"KOBAYASHI, Hidehiko"},{"subitem_text_value":"OGlNO, Hiroyuki"},{"subitem_text_value":"NAKAMURA, Kazumasa"},{"subitem_text_value":"MORI, Toshiyuki"},{"subitem_text_value":"YAMAMURA, Hiroshi"},{"subitem_text_value":"MITAMURA, Takashi"}]},"item_119_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"A1002226"}]},"item_119_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科物質科学部門"},{"subitem_text_value":"埼玉大学工学部応用化学科"},{"subitem_text_value":"埼玉大学工学部応用化学科"},{"subitem_text_value":"東ソー(株)筑波研究所"},{"subitem_text_value":"東ソー(株)筑波研究所"},{"subitem_text_value":"埼玉大学工学部"}]},"item_119_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Department of Applied Chemistry, Faculty of Engineering, Saitama University"},{"subitem_text_value":"Department of Applied Chemistry, Faculty of Engineering, Saitama University"},{"subitem_text_value":"Department of Applied Chemistry, Faculty of Engineering, Saitama University"},{"subitem_text_value":"Tsukuba Laboratory, Tosoh Co., Ltd."},{"subitem_text_value":"Tsukuba Laboratory, Tosoh Co., Ltd."},{"subitem_text_value":"Faculty of Engineering, Saitama University"}]},"item_119_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"1994-6"}]},"item_119_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"小林, 秀彦"},{"creatorName":"コバヤシ, ヒデヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"荻野, 博幸"},{"creatorName":"オギノ, ヒロユキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"中村, 和正"},{"creatorName":"ナカムラ, カズマサ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"森, 利之"},{"creatorName":"モリ, トシユキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"山村, 博"},{"creatorName":"アナムラ, ヒロシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"三田村, 孝"},{"creatorName":"ミタムラ, タカシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"A1002226.pdf","filesize":[{"value":"512.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"A1002226.pdf","url":"https://sucra.repo.nii.ac.jp/record/12976/files/A1002226.pdf"},"version_id":"92e47f64-8e4e-43d9-b868-3d829bc16c85"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"BaM_20_4(M : La,Nd,Sm,Gd,Ho,Y)","subitem_subject_scheme":"Other"},{"subitem_subject":"CaFe_2O_4 structure","subitem_subject_scheme":"Other"},{"subitem_subject":"Oxygen vacancy","subitem_subject_scheme":"Other"},{"subitem_subject":"Order-disorder transition","subitem_subject_scheme":"Other"},{"subitem_subject":"Ionic conductivity","subitem_subject_scheme":"Other"},{"subitem_subject":"Solid electrolyte","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"BaCO_3-M_2O_3混合粉末(M : La, Nd, Sm, Gd, Ho, Y)から反応焼結により合成したBaM_20_4の秩序-無秩序転移","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"BaCO_3-M_2O_3混合粉末(M : La, Nd, Sm, Gd, Ho, Y)から反応焼結により合成したBaM_20_4の秩序-無秩序転移"}]},"item_type_id":"119","owner":"3","path":["426"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-01-09"},"publish_date":"2008-01-09","publish_status":"0","recid":"12976","relation_version_is_last":true,"title":["BaCO_3-M_2O_3混合粉末(M : La, Nd, Sm, Gd, Ho, Y)から反応焼結により合成したBaM_20_4の秩序-無秩序転移"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T12:45:13.896751+00:00"}