@article{oai:sucra.repo.nii.ac.jp:00013132, author = {佐藤, 勝}, issue = {2}, journal = {JOURNAL OF ORGANOMETALLIC CHEMISTRY}, month = {}, note = {http://www.sciencedirect.com/science/journal/0022328X | http://www.sciencedirect.com/science/journal/0022328X, Binuclear ruthenocenes bridged by ethenes and thiophene derivatives, Rc-CH=CH-Z-Rc and Rc*-CH=CH-Z-CH=CH-Rc* (Z = thiophene, thieno[3,2-b]thiophene, and 2,2’-bithiophene; Rc = ruthenocenyl, R* = 1’,2’,3’,4’,5’-pentamethylruthenocenyl) were prepared. These complexes showed a one-step two-electron redox wave in the cyclic voltammograms, in contrast to the benzenoid-bridged dinuclear ruthenocenes. The chemical oxidation of the Rc-CH=CH-Z-Rc complexes gave no stable oxidized species. The two-electron oxidized species of the Rc*-CH=CH-Z-CH=CH-Rc* complexes were comparably stable and contained a fulvene-complex type structure., text, application/pdf}, pages = {247--256}, title = {Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives}, volume = {693}, year = {2008}, yomi = {サトウ, マサル} }