{"created":"2023-05-15T15:25:28.929546+00:00","id":13132,"links":{},"metadata":{"_buckets":{"deposit":"9420805d-0d47-4f6e-8357-6d15552f1406"},"_deposit":{"created_by":3,"id":"13132","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"13132"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00013132","sets":["94:426"]},"author_link":["21077"],"item_119_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"256","bibliographicPageStart":"247","bibliographicVolumeNumber":"693","bibliographic_titles":[{"bibliographic_title":"JOURNAL OF ORGANOMETALLIC CHEMISTRY"}]}]},"item_119_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2008-03-06","subitem_date_issued_type":"Created"}]},"item_119_description_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_description":"http://www.sciencedirect.com/science/journal/0022328X | http://www.sciencedirect.com/science/journal/0022328X","subitem_description_type":"Other"}]},"item_119_description_19":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Binuclear ruthenocenes bridged by ethenes and thiophene derivatives, Rc-CH=CH-Z-Rc and Rc*-CH=CH-Z-CH=CH-Rc* (Z = thiophene, thieno[3,2-b]thiophene, and 2,2’-bithiophene; Rc = ruthenocenyl, R* = 1’,2’,3’,4’,5’-pentamethylruthenocenyl) were prepared. These complexes showed a one-step two-electron redox wave in the cyclic voltammograms, in contrast to the benzenoid-bridged dinuclear ruthenocenes. The chemical oxidation of the Rc-CH=CH-Z-Rc complexes gave no stable oxidized species. The two-electron oxidized species of the Rc*-CH=CH-Z-CH=CH-Rc* complexes were comparably stable and contained a fulvene-complex type structure.","subitem_description_type":"Abstract"}]},"item_119_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_119_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_119_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"ELSEVIER SCIENCE SA"}]},"item_119_relation_16":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1016/j.jorganchem.2007.07.057","subitem_relation_type_select":"DOI"}}]},"item_119_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0022328X","subitem_source_identifier_type":"ISSN"}]},"item_119_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[著者版]"}]},"item_119_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"Sato, Masaru"},{"subitem_text_value":"Kitamura, Tatsumi"},{"subitem_text_value":"Masiko, Tomohiro"},{"subitem_text_value":"Unoura, Kei"}]},"item_119_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"A1002465"}]},"item_119_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学理学部"},{"subitem_text_value":"埼玉大学理学部"},{"subitem_text_value":"埼玉大学理学部"},{"subitem_text_value":"山形大学理学部"}]},"item_119_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry, Faculty of Science, Saitama University"},{"subitem_text_value":"Department of Chemistry, Faculty of Science, Saitama University"},{"subitem_text_value":"Department of Chemistry, Faculty of Science, Saitama University"},{"subitem_text_value":"Department of Chemistry, Faculty of Science, Yamagata university"}]},"item_119_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2008"}]},"item_119_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐藤, 勝"},{"creatorName":"サトウ, マサル","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"A1002465.pdf","filesize":[{"value":"1.2 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"A1002465.pdf","url":"https://sucra.repo.nii.ac.jp/record/13132/files/A1002465.pdf"},"version_id":"95fef4f1-a64a-49a5-9d22-a7872c24dda2"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Ruthenocenes","subitem_subject_scheme":"Other"},{"subitem_subject":"Thiophene derivatives","subitem_subject_scheme":"Other"},{"subitem_subject":"Two-electron redox","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives"}]},"item_type_id":"119","owner":"3","path":["426"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-03-06"},"publish_date":"2008-03-06","publish_status":"0","recid":"13132","relation_version_is_last":true,"title":["Synthesis and some properties of binuclear ruthenocene derivatives bridged by both ethene and thiophene derivatives"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T12:40:10.303443+00:00"}