{"created":"2023-05-15T15:25:29.013150+00:00","id":13134,"links":{},"metadata":{"_buckets":{"deposit":"a35decf5-279a-4843-94c5-1cf466502dfe"},"_deposit":{"created_by":3,"id":"13134","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"13134"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00013134","sets":["94:426"]},"author_link":["21086","21082","21083","21084","21085"],"item_119_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Synthesis and Optical Properties of Nonlinear Optical Materials Containing Carbazole Trimer Units"}]},"item_119_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"1133","bibliographicPageStart":"1127","bibliographicVolumeNumber":"J85-C","bibliographic_titles":[{"bibliographic_title":"電子情報通信学会論文誌. C, エレクトロニクス"}]}]},"item_119_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2008-03-06","subitem_date_issued_type":"Created"}]},"item_119_description_19":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"我々は,多機能性色素としてアクセプタを導入したカルバゾール誘導体に注目し,これらを含む種々の主鎖型ポリマを合成し,その2次非線形光学応答やフォトリフラクティブ効果を検討してきた.一方,分子レベルで光電子機能を制御可能である共役カルバゾールトリマは,中央部と両末端のカルバゾール環で機能が分担されるため,高効率のフォトリフラクティブ効果の発現が得られる.両者の特長を兼ね備えた新規物質としてトリマユニットを有する主鎖型ポリマ及び環状オリゴマの合成に成功した.これらの化合物では主鎖型ポリマや環状オリゴマの連結様式によらず,トリマユニットの光学特性が保持されていた.トリマユニットではモノマユニツトに比べ,吸収スペクトルは10nmブルーシフトし,蛍光スペクトルは100nmレッドシフトした.6500cm^-1の大きな Stokes shiftが観測され,光学特性においてモノマユニットとは明確な差異が得られた.また,高効率な励起エネルギー移動が観測された.トリマユニットを有する主鎖型ポリマは電場配向可能であり,2次非線形光学応答を示すことが確認された.","subitem_description_type":"Abstract"}]},"item_119_description_21":{"attribute_name":"注記","attribute_value_mlt":[{"subitem_description":"copyright(c)2002 IEICE\n許諾番号：08RB0034　http://search.ieice.org/index.html","subitem_description_type":"Other"}]},"item_119_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_119_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_119_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"社団法人電子情報通信学会"}]},"item_119_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"13452827","subitem_source_identifier_type":"ISSN"}]},"item_119_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_119_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"IMASE, Yoshihiro"},{"subitem_text_value":"GUNJI, Atsushi"},{"subitem_text_value":"SASSA, Takafumi"},{"subitem_text_value":"AOYAMA, Tetsuya"},{"subitem_text_value":"WADA, Tatsuo"}]},"item_119_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"A1003129"}]},"item_119_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科 ; 理化学研究所"},{"subitem_text_value":"理化学研究所"},{"subitem_text_value":"理化学研究所"},{"subitem_text_value":"理化学研究所"},{"subitem_text_value":"埼玉大学大学院理工学研究科 ; 理化学研究所"}]},"item_119_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University ; RIKEN (The Institute of Physical & Chemical Research)"},{"subitem_text_value":"RIKEN (The Institute of Physical & Chemical Research)"},{"subitem_text_value":"RIKEN (The Institute of Physical & Chemical Research)"},{"subitem_text_value":"RIKEN (The Institute of Physical & Chemical Research)"},{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University ; RIKEN (The Institute of Physical & Chemical Research)"}]},"item_119_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2002-12"}]},"item_119_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"今瀬, 禎宏"},{"creatorName":"イマセ, ヨシヒロ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"郡司, 敦"},{"creatorName":"グンジ, アツシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"佐々, 高史"},{"creatorName":"サッサ, タカフミ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"青山, 哲也"},{"creatorName":"アオヤマ, テツヤ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"和田, 達夫"},{"creatorName":"ワダ, タツオ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"A1003129.pdf","filesize":[{"value":"534.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"A1003129.pdf","url":"https://sucra.repo.nii.ac.jp/record/13134/files/A1003129.pdf"},"version_id":"c89ef036-8338-4983-9828-2f0ba10f13bd"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"カルバゾール誘導体","subitem_subject_scheme":"Other"},{"subitem_subject":"主鎖型ポリマ","subitem_subject_scheme":"Other"},{"subitem_subject":"2次非線形光学応答","subitem_subject_scheme":"Other"},{"subitem_subject":"Knoevenagel縮合反応","subitem_subject_scheme":"Other"},{"subitem_subject":"環状オリゴマ","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"カルバゾールトリマを含む非線形光学材料の合成と光学特性(有機分子エレクトロニクスの現状と将来展望論文小特集)","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"カルバゾールトリマを含む非線形光学材料の合成と光学特性(有機分子エレクトロニクスの現状と将来展望論文小特集)"}]},"item_type_id":"119","owner":"3","path":["426"],"pubdate":{"attribute_name":"公開日","attribute_value":"2008-03-06"},"publish_date":"2008-03-06","publish_status":"0","recid":"13134","relation_version_is_last":true,"title":["カルバゾールトリマを含む非線形光学材料の合成と光学特性(有機分子エレクトロニクスの現状と将来展望論文小特集)"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T12:40:09.607079+00:00"}