@article{oai:sucra.repo.nii.ac.jp:00013151,
 author = {倉澤, 隆 and 四ツ柳, 隆夫 and 金子, 恵美子 and 齋藤, 伸吾 and 星, 座 and 赤塚, 邦彦},
 issue = {9},
 journal = {分析化学},
 month = {},
 note = {The retention behavior of cationic aluminium chelate with ο,ο'-dihydroxyazobenzene (DHAB or H_2L), [AIL]^+, in high-performance liquid chromatography (HPLC) was investigated using the C_18-bonded silica stationary phase. In this study, it was found that when the pH of the mobile phase was 5.5, a significant tailing of the alminium chelate was observed, whereas when the pH was 2, a marked improvement of the elution was attained. These results were interpreted in terms of a silanol masking effect: when an acidic mobile phase is employed, protonation of the silanol groups on the surface is maintained, while eliminating the strong interaction between the cationic chelate and the stationary phase. The addition of sodium chloride in the eluent can also be used to eliminate peak tailing of the cationic chelate. Based on these results, the underlying immobilization mechanism of the aluminium chelate. Based on these results, the under-lying immobilization mechanism of the aluminium chelate on the C_18-bonded silica thin layer is explained by an electrostatic interaction between the cationic aluminium chelate and deprotonated silanol groups on the solid surface. The example in this study should provide valuable information to improve the separation quality of cationic solutes in HPLC., text, application/pdf},
 pages = {833--836},
 title = {C_18修飾シリカ固定相を用いる高速液体クロマトグラフィーにおけるアルミニウム : ο,ο'-ジヒドロキシアゾベンゼン陽イオン性錯体の保持挙動},
 volume = {51},
 year = {2002},
 yomi = {サイトウ, シンゴ}
}