@article{oai:sucra.repo.nii.ac.jp:00013161,
 author = {YARITA, Takashi and NAKAJIMA, Ryoji and 渋川, 雅美},
 issue = {2},
 journal = {Analytical Sciences},
 month = {},
 note = {A method for the superheated water chromatography of phenols was developed using a poly(styrene-divinylbenzene) (PSDVB) stationary phase. The stationary phase of superheated water chromatography must be stable against the attack of water. A durability test for PSDVB packings and octadecylsilyl (ODS)-silica gels indicated that PSDVB packings were stable in superheated water in the temperature range of 100 - 150°C, whereas octadecylsilyl groups of ODS-silica gels cleaved even at 100°C. The retention of phenols on the PSDVB stationary phase decreased with an elevation of the column temperature. The retention mechanism was characterized using a thermodynamic theory that has been used for describing retention in conventional RP-HPLC. The application of the present method to an environmental analysis was also demonstrated, in which a suitable separation with good peak shape was obtained for p-chlorophenol in river-water samples., text, application/pdf},
 pages = {269--272},
 title = {Superheated water chromatography of phenols using poly(styrene-divinylbenzene) packings as a stationary phase},
 volume = {19},
 year = {2003},
 yomi = {シブカワ, マサミ}
}