@article{oai:sucra.repo.nii.ac.jp:00013239, author = {上野, 啓司 and Uchino, Y and Iizumi, K and Sasaki, Kentaro and 斉木, 幸一朗 and 小間, 篤}, journal = {APPLIED SURFACE SCIENCE}, month = {}, note = {http://www.sciencedirect.com/science/journal/01694332 | http://www.sciencedirect.com/science/journal/01694332, We have investigated the electronic structure of KxC60 (x = 0-6) using low-energy electron energy loss spectroscopy (LEELS), especially focusing on the K-3p core-electron excitation spectra. It is found that the structure of the K-3p-excitation spectrum of KxC60 quite differs from that of KCI. Furthermore, the K-3p-excitation LEELS of K3C60 has been revealed to be different from that of K6C60. K-3p electrons are excited into K-4s- and K-3d-derived empty states in both KxC60 and KCI, but in the case of KxC60 the K-3d-derived empty states have a rather complicated structure where several levels are not well separated. Consequently, K-3p-excitation LEEL spectra of KxC60 show wide-spread plateau-like structures. The difference in the K-3p- excitation spectra of K3C60 and K6C60 is considered to originate from the different crystal field around K+ cations in the C-60 molecular crystal. (C) 2001 Elsevier Science B.V. All rights reserved., text, application/pdf}, pages = {184--187}, title = {Electron-energy-loss spectroscopy of KxC60 and K-halides: comparison in the K-3p excitation region}, volume = {169}, year = {2001}, yomi = {ウエノ, ケイジ and サイキ, コウイチロウ and コマ, アツシ} }