{"created":"2023-05-15T15:25:56.218129+00:00","id":13752,"links":{},"metadata":{"_buckets":{"deposit":"cad2a458-112d-48ad-b27b-eec937656bf0"},"_deposit":{"created_by":3,"id":"13752","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"13752"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00013752","sets":["94:426"]},"author_link":["16699","22978","16489","18278","22977"],"item_119_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Improved Durability of Eu Chelate Encapsulated by Silica Glass Film Prepared by Sol-Gel Method"}]},"item_119_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"11","bibliographicPageEnd":"793","bibliographicPageStart":"790","bibliographicVolumeNumber":"93","bibliographic_titles":[{"bibliographic_title":"照明学会誌"},{"bibliographic_title":"JOURNAL OF THE ILLUMINATING ENGINEERING INSTITUTE OF JAPAN","bibliographic_titleLang":"en"}]}]},"item_119_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2009-11-02","subitem_date_issued_type":"Created"}]},"item_119_description_19":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We demonstrated an improved durability of Eu(HFA)_3(TPPO)_2 [tris(hexafluoroacetylacetonato)- europium(III) 1,2-phenylenebis(diphenylphosphine oxide)] encapsulated by a sol-gel derived silica glass film. The film was constructed using phenyltrimethoxysilane and diethoxy- dimethylsilane as a starting solution. Unlike cases in which conventional tetramethoxysilane is used, no decrease in internal quantum efficiency was observed at room temperature. We further improved the thermal and long-term stability of Eu(HFA)_3(TPPO)_2 inside the transparent glass film at elevated annealing temperatures when compared to the Eu(HFA)_3(TPPO)_2 powder itself: The photoluminescence quantum efficiency of the transparent film was 60% at 160\"C and 32% at 200\"C. Properly prepared glass networks protect the Eu chelate from free oxygen and water in the transparent glass film, which is promising for future practical applications.","subitem_description_type":"Abstract"}]},"item_119_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_119_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_119_other_language_22":{"attribute_name":"その他の言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_119_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"照明学会"}]},"item_119_publisher_12":{"attribute_name":"出版者名（別言語）","attribute_value_mlt":[{"subitem_publisher":"The Illuminating Engineering Institute of Japan"}]},"item_119_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"00192341","subitem_source_identifier_type":"ISSN"}]},"item_119_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_119_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"Yamauchi, Shuhei"},{"subitem_text_value":"Fukuda, Takeshi"},{"subitem_text_value":"Honda, Zentaro"},{"subitem_text_value":"Kijima, Naoto"},{"subitem_text_value":"Kamata, Norihiko"}]},"item_119_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"A1003186"}]},"item_119_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学"},{"subitem_text_value":"埼玉大学大学院理工学研究科物質科学部門"},{"subitem_text_value":"埼玉大学大学院理工学研究科物質科学部門"},{"subitem_text_value":"三菱化学科学技術研究センター"},{"subitem_text_value":"埼玉大学大学院理工学研究科物質科学部門"}]},"item_119_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Saitama University"},{"subitem_text_value":"Department of Functional Materials Science, Saitama University"},{"subitem_text_value":"Department of Functional Materials Science, Saitama University"},{"subitem_text_value":"Mitsubishi Chemical Group, Sci. Tech. Res. Center, Inc."},{"subitem_text_value":"Department of Functional Materials Science, Saitama University"}]},"item_119_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2009"}]},"item_119_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"山内, 修平"},{"creatorName":"ヤマウチ, シュウヘイ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"福田, 武司"},{"creatorName":"フクダ, タケシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"本多, 善太郎"},{"creatorName":"ホンダ, ゼンタロウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"木島, 直人"},{"creatorName":"キジマ, ナオト","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"鎌田, 憲彦"},{"creatorName":"カマタ, ノリヒコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"A1003186.pdf","filesize":[{"value":"726.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"A1003186.pdf","url":"https://sucra.repo.nii.ac.jp/record/13752/files/A1003186.pdf"},"version_id":"c7473ebd-438b-44f5-b7b1-79d1762e9475"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"sol-gel process","subitem_subject_scheme":"Other"},{"subitem_subject":"Eu chelate","subitem_subject_scheme":"Other"},{"subitem_subject":"thermal durability","subitem_subject_scheme":"Other"},{"subitem_subject":"organic-inorganic hybrid material","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ゾルーゲルガラスで封止したEu錯体含有蛍光薄膜の信頼性向上","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ゾルーゲルガラスで封止したEu錯体含有蛍光薄膜の信頼性向上"}]},"item_type_id":"119","owner":"3","path":["426"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-11-02"},"publish_date":"2009-11-02","publish_status":"0","recid":"13752","relation_version_is_last":true,"title":["ゾルーゲルガラスで封止したEu錯体含有蛍光薄膜の信頼性向上"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-16T12:24:30.431453+00:00"}