{"created":"2023-05-15T15:26:32.653434+00:00","id":14585,"links":{},"metadata":{"_buckets":{"deposit":"77d911da-f383-4e09-8050-6016301b3170"},"_deposit":{"created_by":3,"id":"14585","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"14585"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00014585","sets":["95:240:476"]},"author_link":["24932","18643"],"item_120_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Development of new reactions over halide cluster catalysts"}]},"item_120_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"33","bibliographicPageStart":"30","bibliographicVolumeNumber":"3","bibliographic_titles":[{"bibliographic_title":"CACS FORUM"}]}]},"item_120_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2013-03-07","subitem_date_issued_type":"Created"}]},"item_120_description_19":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"Since the first report on MoCl2 (= [Mo6Cl8]Cl2Cl4/2]) in 1859, many halide clusters have been synthesized. As high temperatures (600–1000 °C) are generally required for synthesis of the halide clusters and they are thermally quite stable, attempts to utilize them as catalysts have not yet been made. We have been studying the application of the clusters to catalysis. When halide clusters were thermally activated in a gas stream, a hydroxo ligand and a coordinatively unsaturated site developed on the metal atom. The hydroxo ligand acted as a Brønsted acid to catalyze dehydration of alcohols, ring-attachment isomerization of dialkylbenzenes and methylation of toluene. The metal atom, which accepts some electrons from the halogen ligands and can be isoelectronic with the platinum group metals, catalyzed hydrogenation of alkenes and alkynes, dehydrogenation of cyclohexene and hydrogenolysis of ethylbenzene. In this review, we report on the activities of halide cluster catalysts.","subitem_description_type":"Other"}]},"item_120_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_120_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_120_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00014579","subitem_identifier_reg_type":"JaLC"}]},"item_120_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学研究機構科学分析支援センター"}]},"item_120_publisher_12":{"attribute_name":"出版者名（別言語）","attribute_value_mlt":[{"subitem_publisher":"Comprehensive Analysis Center for Science, Saitama University"}]},"item_120_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_120_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"NAGASHIMA, Sayoko"},{"subitem_text_value":"CHIHARA, Teiji"}]},"item_120_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"KY-AA12504266-03-06"}]},"item_120_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科物質科学部門"},{"subitem_text_value":"埼玉大学大学院理工学研究科物質科学部門"}]},"item_120_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"},{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"}]},"item_120_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2012-12"}]},"item_120_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"長島, 佐代子"},{"creatorName":"ナガシマ, サヨコ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"千原, 貞次"},{"creatorName":"チハラ, テイジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"KY-AA12504266-03-06.pdf","filesize":[{"value":"497.6 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KY-AA12504266-03-06.pdf","url":"https://sucra.repo.nii.ac.jp/record/14585/files/KY-AA12504266-03-06.pdf"},"version_id":"cf7b47d8-0eee-41bd-af66-995e51e31044"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ハライドクラスター錯体を触媒とする新規反応開発《若手研究者の紹介》","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ハライドクラスター錯体を触媒とする新規反応開発《若手研究者の紹介》"}]},"item_type_id":"120","owner":"3","path":["476"],"pubdate":{"attribute_name":"公開日","attribute_value":"2013-03-08"},"publish_date":"2013-03-08","publish_status":"0","recid":"14585","relation_version_is_last":true,"title":["ハライドクラスター錯体を触媒とする新規反応開発《若手研究者の紹介》"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-15T18:26:26.912491+00:00"}