{"created":"2023-05-15T15:26:33.916354+00:00","id":14615,"links":{},"metadata":{"_buckets":{"deposit":"6c1fdc7c-ecb1-453e-85f3-ff8aec73f0da"},"_deposit":{"created_by":3,"id":"14615","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"14615"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00014615","sets":["95:240:477"]},"author_link":["24956"],"item_120_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Catalysts of metal cluster complexes"}]},"item_120_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2013","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"9","bibliographicPageStart":"2","bibliographicVolumeNumber":"4","bibliographic_titles":[{"bibliographic_title":"CACS FORUM"}]}]},"item_120_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2014-02-18","subitem_date_issued_type":"Created"}]},"item_120_description_19":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"Our application of cluster complexes to catalysis has been reviewed. First, carbonyl clusters are applied to catalysis. Methylation of thermally stable [Ru₆C(CO)₁₆]²⁻ with methyl iodide at 120 ℃ yields [Ru₆C(CO)₁₆(CH₃)]⁻, which provides coordinatively unsaturated hydrido cluster [Ru₆C(CO)₁₅H]⁻ by reaction with hydrogen at 100 ℃. This cluster is an active catalyst for the hydrogenation and isomerization of olefins at 60 ℃. However, we fail to isolate more deeply unsaturated cluster complexes as single crystals. These carbonyl clusters decompose below 200 ℃. In the case of halide clusters such as Mo₆Cl₁₂, treatment in a hydrogen or helium stream at temperatures above 150 ℃ developes catalytic activities with retention of the cluster metal frameworks. Hydroxy groups formed by elimination of hydrogen halide from halogen and aqua ligands exhibit weak Brønsted acidity, and uncoordinated metal atoms exhibits platinum-like catalysis. The catalytic activities are stable as high as 400 ℃. Thus, carbonyl and halide cluster complexes exhibit different behavior as catalysts.","subitem_description_type":"Other"}]},"item_120_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_120_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_120_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00014609","subitem_identifier_reg_type":"JaLC"}]},"item_120_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学研究機構科学分析支援センター"}]},"item_120_publisher_12":{"attribute_name":"出版者名（別言語）","attribute_value_mlt":[{"subitem_publisher":"Comprehensive Analysis Center for Science, Saitama University"}]},"item_120_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_120_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"CHIHARA, Teiji"}]},"item_120_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"KY-AA12504266-04-02"}]},"item_120_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科物質科学部門"}]},"item_120_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"}]},"item_120_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2013-12"}]},"item_120_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"千原, 貞次"},{"creatorName":"チハラ, テイジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"KY-AA12504266-04-02.pdf","filesize":[{"value":"1.3 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KY-AA12504266-04-02.pdf","url":"https://sucra.repo.nii.ac.jp/record/14615/files/KY-AA12504266-04-02.pdf"},"version_id":"b3df76de-8e95-450f-9520-f3ec4c2fc56b"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"金属クラスター錯体触媒《マイレビュー》","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"金属クラスター錯体触媒《マイレビュー》"}]},"item_type_id":"120","owner":"3","path":["477"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-02-18"},"publish_date":"2014-02-18","publish_status":"0","recid":"14615","relation_version_is_last":true,"title":["金属クラスター錯体触媒《マイレビュー》"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-15T18:25:20.847836+00:00"}