@article{oai:sucra.repo.nii.ac.jp:00014857, author = {斎藤, 雅一 and 時任, 宣博 and 岡崎, 廉治}, journal = {CACS FORUM}, month = {}, note = {Stannanethione, Tbt(mes)Sn=S (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Mes = mesityl) was aynthesized by the reaction of the corresponding kinetically stabilized diarylstannylene, Tbt(Mes)Sn:, with styrene episulfide. In THF-Et2O, Tbt(mes)Sn=S reacted with styrene oxide to give the corresponding [3+2]cycloadducts even at room temperature as in the case of more hindered stable stannanethione, Tbt(Tip)Sn=S (Tip = 2,4,6-triisopropylphenyl). On the contrary, Tbt(Mes)Sn=S dimerized in hexane at room temperature to afford the corresponding 1,3,2,4,-dithiadistannetanes, indicating the importance of the solvent effect on the dimerization of Tbt(Mes)Sn=S., text, application/pdf}, pages = {30--32}, title = {溶媒に依存したスタンナンチオンの安定性<ミニノート>}, volume = {18}, year = {1998}, yomi = {サイトウ, マサイチ and トキトウ, ノリヒロ and オカザキ, レンジ} }