@article{oai:sucra.repo.nii.ac.jp:00014866, author = {今野, 英雄 and 小林, 篤生 and 坂本, 和彦 and 石谷, 治}, journal = {CACS FORUM}, month = {}, note = {Two ruthenium pyridine complexes [Ru(tpy)(bpy)(py)]2+ (tpy = 2,2':6',2" -terpyridine, bpy = 2,2'-bipyridine, py = pyridine) and [Ru(bpy)2(py)2]2+ photocatalyzed the regiocontrolled reduction of 1-benzyl-3-carbamoyl-pyridinium cation to the dihydro form (BNAH) with no formation of half-reduced dimers, and BNAH was not consumed even after long-period irradiation. The regioselectivity of photocatalysis proceeds through the prior photosubstitution of a py ligand of the Ru complexes and the subsequent photoformation of [Ru(tpy)(bpy)H]+ or [Ru(bpy)2(py)H]+., text, application/pdf}, pages = {2--8}, title = {ヒドリド移動を選択的に駆動する光触媒<総説 マイレビュー>}, volume = {19}, year = {1999}, yomi = {コンノ, ヒデオ and コバヤシ, アツオ and サカモト, カズヒコ and イシタニ, オサム} }