{"created":"2023-05-15T15:26:45.359498+00:00","id":14886,"links":{},"metadata":{"_buckets":{"deposit":"3defb167-6d30-456b-af2b-12563532636b"},"_deposit":{"created_by":3,"id":"14886","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"14886"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00014886","sets":["95:240:496:493"]},"author_link":["25170"],"item_120_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Innovation of Ketene Chemistry. Big Faults in Ketene History and the Solutions."}]},"item_120_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2000","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"40","bibliographicPageStart":"29","bibliographicVolumeNumber":"20","bibliographic_titles":[{"bibliographic_title":"CACS FORUM"}]}]},"item_120_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2009-11-20","subitem_date_issued_type":"Created"}]},"item_120_description_19":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"Ever since the first discovery of ketene and its cycloaddition by Staudinger in an early year of this century, an explosive number of studies on ketene reaction has been devoted to developing the reaction.  Neverthless, ketene cycloaddition has long been an important problem in organic chemistry.  The problems include the nonrecognition for dienes (4π system) and facile reactivity of forbidden-[2 + 2] cycloaddition for olefins (2π system) and unpredictability of product structures.  It is still hard to predict whether a certain set of reactants will be successful or not.  Modest structural alterations sometimes nullify the capacity of the reaction.  Recently, the author and his coworkers have discovered that ketene reacts across its C=O bond, not the C=C one.  Based on the result, they are solving the remaining problems in the chemistry.  This review outlines the long history of ketene chemistry and describes the way of how the problems have been tackled.","subitem_description_type":"Other"}]},"item_120_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_120_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_120_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00014880","subitem_identifier_reg_type":"JaLC"}]},"item_120_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学分析センター"}]},"item_120_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_120_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"MACHIGUCHI, Takahisa"}]},"item_120_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"KY-AN10402595-20-08"}]},"item_120_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学理学部基礎化学科"}]},"item_120_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry, Faculty of Science, Saitama University"}]},"item_120_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2000-11"}]},"item_120_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"町口, 孝久"},{"creatorName":"マチグチ, タカヒサ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"KY-AN10402595-20-08.pdf","filesize":[{"value":"707.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KY-AN10402595-20-08.pdf","url":"https://sucra.repo.nii.ac.jp/record/14886/files/KY-AN10402595-20-08.pdf"},"version_id":"c2d31c6e-da8e-40b5-a818-2c61cdd1eef8"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ケテン化学の革新(歴史的な大きい誤りとその解決)<総説　レビュー>","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ケテン化学の革新(歴史的な大きい誤りとその解決)<総説　レビュー>"}]},"item_type_id":"120","owner":"3","path":["493"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-11-12"},"publish_date":"2009-11-12","publish_status":"0","recid":"14886","relation_version_is_last":true,"title":["ケテン化学の革新(歴史的な大きい誤りとその解決)<総説　レビュー>"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-15T17:48:20.270583+00:00"}