@article{oai:sucra.repo.nii.ac.jp:00014919,
 author = {藤原, 隆司 and 永澤, 明},
 journal = {CACS FORUM},
 month = {},
 note = {The carboxylate-bridged trinuclear metal complex ions undergo the substitution of unidentate ligands (L) at the terminal sites, while the bridging carboxylato and the central m3-oxo ligands are inert (Type I: n = 1; M = Cr, Co, Ru, Rh. Type II: n = 2; M = Mo, W). 
[M3(m3-O)n(m-RCO2)6(L)3]m+ + 3 L'　→　[M3(m3-O)n(m-RCO2)6(L')3]m+ + 3L
We have kinetically studied the substitution reactions for the terminal ligands in the complexes of Group 6 metals, and discussed the results in relevance to their structures to reveal the mutual ligand effects of the capping m3-oxide and the bridging carboxylates., text, application/pdf},
 pages = {2--9},
 title = {カルボン酸イオン架橋遷移金属三核錯体の単座配位子置換速度におよぼす置換基の電子的・立体的効果<総説　レビュー>},
 volume = {22},
 year = {2002}
}