{"created":"2023-05-15T15:26:46.868898+00:00","id":14919,"links":{},"metadata":{"_buckets":{"deposit":"5ba2f531-d485-4061-afeb-7f6112b475cd"},"_deposit":{"created_by":3,"id":"14919","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"14919"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00014919","sets":["95:240:496:495"]},"author_link":["18313","25202"],"item_120_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Electronic and Steric Effects of the Substituents on the Rate of Unidentate Exchange in Carboxylate-Bridged Trinuclear Metal Complexes"}]},"item_120_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2002","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"9","bibliographicPageStart":"2","bibliographicVolumeNumber":"22","bibliographic_titles":[{"bibliographic_title":"CACS FORUM"}]}]},"item_120_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2009-11-18","subitem_date_issued_type":"Created"}]},"item_120_description_19":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"The carboxylate-bridged trinuclear metal complex ions undergo the substitution of unidentate ligands (L) at the terminal sites, while the bridging carboxylato and the central m3-oxo ligands are inert (Type I: n = 1; M = Cr, Co, Ru, Rh. Type II: n = 2; M = Mo, W). \n[M3(m3-O)n(m-RCO2)6(L)3]m+ + 3 L'　→　[M3(m3-O)n(m-RCO2)6(L')3]m+ + 3L\nWe have kinetically studied the substitution reactions for the terminal ligands in the complexes of Group 6 metals, and discussed the results in relevance to their structures to reveal the mutual ligand effects of the capping m3-oxide and the bridging carboxylates.","subitem_description_type":"Other"}]},"item_120_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_120_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_120_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00014913","subitem_identifier_reg_type":"JaLC"}]},"item_120_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学分析センター"}]},"item_120_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_120_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"FUJIHARA, Takashi"},{"subitem_text_value":"NAGASAWA, Akira"}]},"item_120_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"KY-AN10402595-22-02"}]},"item_120_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学理学部基礎化学科"},{"subitem_text_value":"埼玉大学理学部基礎化学科"}]},"item_120_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry, Faculty of Science, Saitama University"},{"subitem_text_value":"Department of Chemistry, Faculty of Science, Saitama University"}]},"item_120_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2002-12"}]},"item_120_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"藤原, 隆司"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"永澤, 明"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"KY-AN10402595-22-02.pdf","filesize":[{"value":"420.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KY-AN10402595-22-02.pdf","url":"https://sucra.repo.nii.ac.jp/record/14919/files/KY-AN10402595-22-02.pdf"},"version_id":"342c1173-948d-4711-add7-0493f0bde03e"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"カルボン酸イオン架橋遷移金属三核錯体の単座配位子置換速度におよぼす置換基の電子的・立体的効果<総説　レビュー>","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"カルボン酸イオン架橋遷移金属三核錯体の単座配位子置換速度におよぼす置換基の電子的・立体的効果<総説　レビュー>"}]},"item_type_id":"120","owner":"3","path":["495"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-11-12"},"publish_date":"2009-11-12","publish_status":"0","recid":"14919","relation_version_is_last":true,"title":["カルボン酸イオン架橋遷移金属三核錯体の単座配位子置換速度におよぼす置換基の電子的・立体的効果<総説　レビュー>"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-05-15T17:47:07.440469+00:00"}