{"created":"2023-05-15T15:26:49.637781+00:00","id":14985,"links":{},"metadata":{"_buckets":{"deposit":"2e165052-c2eb-44cd-89d8-82edf769362f"},"_deposit":{"created_by":3,"id":"14985","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"14985"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00014985","sets":["95:241:514"]},"author_link":["25237","25236"],"item_120_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Synthesis of Ruthenocenyl–substituted Tetrathiafulvalene"}]},"item_120_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"7","bibliographicPageStart":"3","bibliographicVolumeNumber":"5","bibliographic_titles":[{"bibliographic_title":"MaLS FORUM"}]}]},"item_120_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2010-01-29","subitem_date_issued_type":"Created"}]},"item_120_description_19":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"4–Ruthenocenyl–1,3–dithiol–2–thione was obtained in 62 % yield from the reaction of ethynylruthenocene with n–BuLi / S8 and subsequently CS2. Desulfurizing coupling of 4–ruthenocenyl–1,3–dithiol–2–thione was unsuccessful. 4–Ruthenocenyl–1,3–dithiol–2– thione was oxidized with Hg(OAc)2 to give 4–ruthenocenyl–1,3–dithiol–2–one in good yield. Deoxygenating coupling of 4–ruthenocenyl–1,3–dithiol–2–one afforded bis(ruthenocenyl) tetrathiafulvalene in 17% yield. The oxidation wave due to tetratiafulvalene in this complex shifted to a lower potential region compared with the parent compound.\nルテノセンは不可逆な2 電子酸化反応を受けるが，1 不飽和化合物で架橋された2 核ルテノセン誘導体は，可逆的な1 段階の2 電子酸化還元系に変身する．これまでに，エチレン，2 アセチレン，3 ベンゼン，4 チオフェン架橋について検討してきた．5 その結果，オレフィン性が高く，電子豊富な架橋ほど2 電子酸化を受けやすいことを明らかにしてきた．今回，電子豊富な不飽和化合物であるテトラチアフルバレンで架橋された2 核ルテノセン誘導体の合成を行い，その性質を検討したので報告する．","subitem_description_type":"Other"}]},"item_120_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_120_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_120_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00014979","subitem_identifier_reg_type":"JaLC"}]},"item_120_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学科学分析支援センター"}]},"item_120_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_120_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"Masaru SATO"},{"subitem_text_value":"Toru NAGATA"}]},"item_120_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"KY-AA11910807-05-02"}]},"item_120_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科物質科学部門"},{"subitem_text_value":"埼玉大学大学院理工学研究科物質科学部門"}]},"item_120_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Department of Chemistry, Faculty of Science, Saitama University"},{"subitem_text_value":"Department of Chemistry, Faculty of Science, Saitama University"}]},"item_120_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2008-1"}]},"item_120_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"佐藤, 勝"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"長田, 亨"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"KY-AA11910807-05-02.pdf","filesize":[{"value":"259.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KY-AA11910807-05-02.pdf","url":"https://sucra.repo.nii.ac.jp/record/14985/files/KY-AA11910807-05-02.pdf"},"version_id":"bd009198-7593-4154-b235-4a592a892ca8"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"ルテノセンで置換されたテトラチアフルバレンの合成《機器分析分野》","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ルテノセンで置換されたテトラチアフルバレンの合成《機器分析分野》"}]},"item_type_id":"120","owner":"3","path":["514"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-01-29"},"publish_date":"2010-01-29","publish_status":"0","recid":"14985","relation_version_is_last":true,"title":["ルテノセンで置換されたテトラチアフルバレンの合成《機器分析分野》"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-05-15T18:19:38.557152+00:00"}