@article{oai:sucra.repo.nii.ac.jp:00016118,
 author = {塚越, 康之 and 森, 健治 and 大友, 昭典 and 大嶋, 正明 and 黒川, 秀樹 and 杉山, 和夫 and 三浦, 弘},
 journal = {埼玉大学紀要. 工学部 第1編 第1部 論文集, The Science and Engineering Reports of Saitama University},
 month = {},
 note = {Selective hydrogenation of the C=O bond of α,β-unsaturated aldehyde to form unsaturated alcohol was tried in liquid phase over C_O/Al_2O_3 catalysts. When C_O/Al_2O_3 was prepared from C_O(NO3)2, and Cl-free, activity and selectivity to form unsaturated alcohol was low. Addition of C_OCl_2 in the reaction mixture promoted the selective hydrogenation remarkably. Concentration of Cl in the liquid phase was determined, as well as the amount of adsorbed Cl. A clear relation was found between the C=O hydrogenation activity and the amount of adsorbed Cl. When C_O/Al_2O_3 was prepared from C_oCl_2, Cl remained in the catalyst even after reduction treatment. This catalyst suggested both high activity and selectivity toward unsaturated alcohol formation. The role of chloride ion, existing on the catalyst surface, in selective hydrogenation was discussed., text, application/pdf},
 pages = {54--57},
 title = {C_O/Al_2O_3 触媒を用いた(E)-2-ブテナール水素化反応におけるC_oCl_2の助触媒効果<論文>},
 volume = {39},
 year = {2006},
 yomi = {ツカゴシ, ヤスユキ and モリ, ケンジ and オオトモ, アキノリ and オオシマ, マサアキ and クロカワ, ヒデキ and スギヤマ, カズオ and ミウラ, ヒロシ}
}