{"created":"2023-05-15T15:27:21.305142+00:00","id":16118,"links":{},"metadata":{"_buckets":{"deposit":"5079fb09-129f-4147-bdb9-53d3fb106edd"},"_deposit":{"created_by":3,"id":"16118","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"16118"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00016118","sets":["89:355:518"]},"author_link":["26228","16568","26229","26227","26230","26226","26231"],"item_120_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Promoting Effect of C_oCl_2 on the Hydrogenation of (E)-2-butenal over Co/Al_2O_3 Catalysts"}]},"item_120_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2006","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"57","bibliographicPageStart":"54","bibliographicVolumeNumber":"39","bibliographic_titles":[{"bibliographic_title":"埼玉大学紀要. 工学部 第1編 第1部 論文集"},{"bibliographic_title":"The Science and Engineering Reports of Saitama University","bibliographic_titleLang":"en"}]}]},"item_120_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2008-03-19","subitem_date_issued_type":"Created"}]},"item_120_description_19":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"Selective hydrogenation of the C=O bond of α,β-unsaturated aldehyde to form unsaturated alcohol was tried in liquid phase over C_O/Al_2O_3 catalysts. When C_O/Al_2O_3 was prepared from C_O(NO3)2, and Cl-free, activity and selectivity to form unsaturated alcohol was low. Addition of C_OCl_2 in the reaction mixture promoted the selective hydrogenation remarkably. Concentration of Cl in the liquid phase was determined, as well as the amount of adsorbed Cl. A clear relation was found between the C=O hydrogenation activity and the amount of adsorbed Cl. When C_O/Al_2O_3 was prepared from C_oCl_2, Cl remained in the catalyst even after reduction treatment. This catalyst suggested both high activity and selectivity toward unsaturated alcohol formation. The role of chloride ion, existing on the catalyst surface, in selective hydrogenation was discussed.","subitem_description_type":"Other"}]},"item_120_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_120_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_120_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00016112","subitem_identifier_reg_type":"JaLC"}]},"item_120_other_language_22":{"attribute_name":"その他の言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_120_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学工学部"}]},"item_120_publisher_12":{"attribute_name":"出版者名（別言語）","attribute_value_mlt":[{"subitem_publisher":"Faculty of Engineering, Saitama University"}]},"item_120_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18804446","subitem_source_identifier_type":"ISSN"}]},"item_120_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_120_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"TSUKAGOSHI, Yasuyuki"},{"subitem_text_value":"MORI, Kenji"},{"subitem_text_value":"OHTOMO, Akinori"},{"subitem_text_value":"OHSHIMA, Masaaki"},{"subitem_text_value":"KUROKAWA, Hideki"},{"subitem_text_value":"SUGIYAMA, Kazuo"},{"subitem_text_value":"MIURA, Hiroshi"}]},"item_120_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"KY-AN00095842-39-09"}]},"item_120_text_4":{"attribute_name":"著者 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University"}]},"item_120_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2006-7"}]},"item_120_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"塚越, 康之"},{"creatorName":"ツカゴシ, ヤスユキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"森, 健治"},{"creatorName":"モリ, ケンジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"大友, 昭典"},{"creatorName":"オオトモ, アキノリ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"大嶋, 正明"},{"creatorName":"オオシマ, マサアキ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"黒川, 秀樹"},{"creatorName":"クロカワ, 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触媒を用いた(E)-2-ブテナール水素化反応におけるC_oCl_2の助触媒効果<論文>"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-15T18:51:09.965174+00:00"}