{"created":"2023-05-15T15:27:33.939080+00:00","id":16418,"links":{},"metadata":{"_buckets":{"deposit":"c11fadc4-3e23-414d-88b5-1ccb7b8d0d7f"},"_deposit":{"created_by":3,"id":"16418","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"16418"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00016418","sets":["89:355:520"]},"author_link":["17850","26569"],"item_120_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Study on heterogeneous reactions between tar and ash during coal gasification"}]},"item_120_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2007","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"14","bibliographicPageStart":"10","bibliographicVolumeNumber":"41","bibliographic_titles":[{"bibliographic_title":"埼玉大学工学部紀要 第一部 論文集"}]}]},"item_120_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2014-02-24","subitem_date_issued_type":"Created"}]},"item_120_description_19":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"In coal gasification, it is one of the problems to sub-generated tar. To solve this trouble, we focus attention on that major components of ash contain calcium oxide (CaO) that is known as catalyst can decompose tar, and thought whether the tar was able to be decreased by using the ash in gasification furnace. The purpose of this study is to demonstrate reactions between tar and ash during coal gasification, and to estimate effect of tar decrease by ash.\nIn this study, toluene, CaO, and Carbide from phenol resin was selected as the model tar, model ash, and model carbon, respectively. Experiments were carried out by passing toluene to CaO in flow fixed-bed reactor under increasing temperature (25～900 ℃, 10 ℃/min), and under constant temperature (700 ℃ and 900 ℃) for 5 h. As a result, it is turn out that CaO is effective to decreasing toluene. The rate constant when toluene decompose with CaO is about 58 times as large as rate constant when toluene decompose without CaO at 700 ℃, is about 30 times at 900 ℃. Also, although model carbon didn’t affect toluene conversion, when toluene decompose with CaO combined model carbon, benzene yield is decreased from it when toluene decompose with nothing.","subitem_description_type":"Other"}]},"item_120_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_120_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_120_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00016412","subitem_identifier_reg_type":"JaLC"}]},"item_120_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学工学部"}]},"item_120_publisher_12":{"attribute_name":"出版者名（別言語）","attribute_value_mlt":[{"subitem_publisher":"Faculty of Engineering, Saitama University"}]},"item_120_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_120_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"WANG, Qingyue"},{"subitem_text_value":"IKODA, Kosuke"}]},"item_120_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"KY-AN00095842-41-02"}]},"item_120_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科環境科学・社会基盤部門"}]},"item_120_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"}]},"item_120_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2007"}]},"item_120_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"王, 青躍"},{"creatorName":"オウ, セイヨウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"井古田, 亘佑"},{"creatorName":"イコダ, コウスケ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"KY-AN00095842-41-02.pdf","filesize":[{"value":"421.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KY-AN00095842-41-02.pdf","url":"https://sucra.repo.nii.ac.jp/record/16418/files/KY-AN00095842-41-02.pdf"},"version_id":"bbad4551-8e42-4f75-9f06-5c8c46f90bc5"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"coal gasification","subitem_subject_scheme":"Other"},{"subitem_subject":"pyrolysis","subitem_subject_scheme":"Other"},{"subitem_subject":"tar","subitem_subject_scheme":"Other"},{"subitem_subject":"ash","subitem_subject_scheme":"Other"},{"subitem_subject":"toluene","subitem_subject_scheme":"Other"},{"subitem_subject":"calcium oxide","subitem_subject_scheme":"Other"},{"subitem_subject":"heterogeneous reaction","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"石炭ガス化におけるタールと灰分との不均一反応に関する基礎研究＜論文＞","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"石炭ガス化におけるタールと灰分との不均一反応に関する基礎研究＜論文＞"}]},"item_type_id":"120","owner":"3","path":["520"],"pubdate":{"attribute_name":"公開日","attribute_value":"2014-02-24"},"publish_date":"2014-02-24","publish_status":"0","recid":"16418","relation_version_is_last":true,"title":["石炭ガス化におけるタールと灰分との不均一反応に関する基礎研究＜論文＞"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-15T18:49:56.949034+00:00"}