@article{oai:sucra.repo.nii.ac.jp:00016474,
 author = {石井, 昭彦 and 中田, 憲男 and 芦田, 彪 and 加藤, 淳一 and 新井, 輝明 and 森, さやか},
 journal = {埼玉大学地域オープンイノベーションセンター紀要, Report of Comprehensive Open Innovation Center, Saitama University},
 month = {},
 note = {The oxidative addition of [Pt(2-nb)(PPh3)2] with a sterically hindered thiol TripSH (Trip = 9-triptycyl) in toluene afforded cis-hydrido(thiolato) Pt(II) complex PtH(Strip)(PPh3)2 as thermally and moisture stable colorless crystals in 91% yield. The thermal reaction of PtH(Strip)(PPh3)2 gave the corresponding thiaplatinacycle. The first stable dihydrogermyl(hydrido) platinum(II) complex PtH(GeH2Trip)(Ph3P)2 was synthesized by the oxidative addition reaction of TripGeH3 with Pt( 2-C2H4)(Ph3P)2 in toluene. The reaction of TripGeH3 with (dppe)PtCl2 in the presence of NaBH4 afforded the corresponding hydrido complex PtH(GeH2Trip)(dppe) together with bis(germyl) platinum(II) complex Pt(GeH2Trip)2(dppe). The ligand exchange reaction of PtH(GeH2Trip)(Ph3P)2 with Cy2PCH2CH2PCy2 (DCPE) in toluene resulted in the formation of PtH(GeH2Trip)(dcpe) in the moderate yield. Thermal rearrangement of Pt(GeH2Trip)2(dppe) in toluene at 60 ˚C gave digermyl(hydrido) complex PtH[Ge(Htrip)GeH2Trip](dppe) in high yield., text, application/pdf},
 pages = {30--32},
 title = {遷移金属錯体触媒を用いる効率的・選択的合成反応の研究},
 volume = {1},
 year = {2009}
}