{"created":"2023-05-15T15:27:36.241941+00:00","id":16474,"links":{},"metadata":{"_buckets":{"deposit":"ba1f50a2-a94c-497d-82da-be9e984692b9"},"_deposit":{"created_by":3,"id":"16474","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"16474"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00016474","sets":["95:238:630"]},"author_link":["26668","26669","18298","26667","18381","26670"],"item_120_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Study on the Effective and Selective Synthetic Reaction with Transition Metal Catalysts"}]},"item_120_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2009","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"32","bibliographicPageStart":"30","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"埼玉大学地域オープンイノベーションセンター紀要"},{"bibliographic_title":"Report of Comprehensive Open Innovation Center, Saitama University","bibliographic_titleLang":"en"}]}]},"item_120_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2009-08-18","subitem_date_issued_type":"Created"}]},"item_120_description_19":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"The oxidative addition of [Pt(2-nb)(PPh3)2] with a sterically hindered thiol TripSH (Trip = 9-triptycyl) in toluene afforded cis-hydrido(thiolato) Pt(II) complex PtH(Strip)(PPh3)2 as thermally and moisture stable colorless crystals in 91% yield. The thermal reaction of PtH(Strip)(PPh3)2 gave the corresponding thiaplatinacycle. The first stable dihydrogermyl(hydrido) platinum(II) complex PtH(GeH2Trip)(Ph3P)2 was synthesized by the oxidative addition reaction of TripGeH3 with Pt( 2-C2H4)(Ph3P)2 in toluene. The reaction of TripGeH3 with (dppe)PtCl2 in the presence of NaBH4 afforded the corresponding hydrido complex PtH(GeH2Trip)(dppe) together with bis(germyl) platinum(II) complex Pt(GeH2Trip)2(dppe). The ligand exchange reaction of PtH(GeH2Trip)(Ph3P)2 with Cy2PCH2CH2PCy2 (DCPE) in toluene resulted in the formation of PtH(GeH2Trip)(dcpe) in the moderate yield. Thermal rearrangement of Pt(GeH2Trip)2(dppe) in toluene at 60 ˚C gave digermyl(hydrido) complex PtH[Ge(Htrip)GeH2Trip](dppe) in high yield.","subitem_description_type":"Other"}]},"item_120_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_120_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_120_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00016468","subitem_identifier_reg_type":"JaLC"}]},"item_120_other_language_22":{"attribute_name":"その他の言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_120_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学総合研究機構地域オープンイノベーションセンター"}]},"item_120_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18838278","subitem_source_identifier_type":"ISSN"}]},"item_120_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_120_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"Ishii, Akihiko"},{"subitem_text_value":"Nakata, Norio"},{"subitem_text_value":"Ashida, Takeshi"},{"subitem_text_value":"Kato, Jun-ichi"},{"subitem_text_value":"Arai, Teruaki"},{"subitem_text_value":"Mori, Sayaka"}]},"item_120_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"KY-18838278-12"}]},"item_120_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科"},{"subitem_text_value":"埼玉大学大学院理工学研究科"},{"subitem_text_value":"株式会社ハイテック"},{"subitem_text_value":"株式会社ハイテック"},{"subitem_text_value":"株式会社ハイテック"},{"subitem_text_value":"株式会社ハイテック"}]},"item_120_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"},{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"},{"subitem_text_value":"Hitec Co., Ltd"},{"subitem_text_value":"Hitec Co., Ltd"},{"subitem_text_value":"Hitec Co., Ltd"},{"subitem_text_value":"Hitec Co., Ltd"}]},"item_120_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2008"}]},"item_120_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"石井, 昭彦"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"中田, 憲男"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"芦田, 彪"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"加藤, 淳一"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"新井, 輝明"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"森, さやか"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"KY-18838278-12.pdf","filesize":[{"value":"329.4 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KY-18838278-12.pdf","url":"https://sucra.repo.nii.ac.jp/record/16474/files/KY-18838278-12.pdf"},"version_id":"98e7dc39-5f88-45ec-8853-5703028116e8"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"Platinum","subitem_subject_scheme":"Other"},{"subitem_subject":"Sulfur","subitem_subject_scheme":"Other"},{"subitem_subject":"Germanium","subitem_subject_scheme":"Other"},{"subitem_subject":"Hydrido complex","subitem_subject_scheme":"Other"},{"subitem_subject":"Metallacycle","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"遷移金属錯体触媒を用いる効率的・選択的合成反応の研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"遷移金属錯体触媒を用いる効率的・選択的合成反応の研究"}]},"item_type_id":"120","owner":"3","path":["630"],"pubdate":{"attribute_name":"公開日","attribute_value":"2009-08-18"},"publish_date":"2009-08-18","publish_status":"0","recid":"16474","relation_version_is_last":true,"title":["遷移金属錯体触媒を用いる効率的・選択的合成反応の研究"],"weko_creator_id":"3","weko_shared_id":3},"updated":"2023-05-15T18:05:43.653379+00:00"}