{"created":"2023-05-15T15:27:38.359460+00:00","id":16524,"links":{},"metadata":{"_buckets":{"deposit":"7249d3d3-7de7-4153-ac4a-09c480d8ef35"},"_deposit":{"created_by":3,"id":"16524","owners":[3],"pid":{"revision_id":0,"type":"depid","value":"16524"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00016524","sets":["95:238:631"]},"author_link":["26802","18587","18415","26801","26803"],"item_120_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Chirality control by substituents in the asymmetric addition of Et2Zn to aromatic aldehydes catalyzed by cis-(1R,2S)-2-benzamidocyclohexanecarboxylic acid derived 1,3-aminoalcohols"}]},"item_120_biblio_info_8":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2010","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"45","bibliographicPageStart":"39","bibliographicVolumeNumber":"2","bibliographic_titles":[{"bibliographic_title":"埼玉大学地域オープンイノベーションセンター紀要"},{"bibliographic_title":"Report of Comprehensive Open Innovation Center, Saitama University","bibliographic_titleLang":"en"}]}]},"item_120_date_31":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2010-07-30","subitem_date_issued_type":"Created"}]},"item_120_description_19":{"attribute_name":"概要","attribute_value_mlt":[{"subitem_description":"A series of novel optically active 1,3-aminoalcohols based on cis-(1R,2S)-2-benzamido- cyclohexanecarboxylic acid and trans-(1R,2R)-2-benzamidocyclohexanecarboxylic acid were synthesized and used in the asymmetric diethylzinc addition to aromatic aldehydes. Not only the enantioselectivity but also the stereochemistry of the product were\ncontrolled by the N-substituents and the substituents on the vicinity carbon to hydroxyl group of the cis-derivatives.","subitem_description_type":"Other"}]},"item_120_description_29":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"subitem_description":"text","subitem_description_type":"Other"}]},"item_120_description_30":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_120_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.24561/00016518","subitem_identifier_reg_type":"JaLC"}]},"item_120_publisher_11":{"attribute_name":"出版者名","attribute_value_mlt":[{"subitem_publisher":"埼玉大学総合研究機構地域オープンイノベーションセンター"}]},"item_120_source_id_14":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"18838278","subitem_source_identifier_type":"ISSN"}]},"item_120_text_27":{"attribute_name":"版","attribute_value_mlt":[{"subitem_text_value":"[出版社版]"}]},"item_120_text_3":{"attribute_name":"著者 ローマ字","attribute_value_mlt":[{"subitem_text_value":"HIROSE, Takuji"},{"subitem_text_value":"WANG, Xiangbo"},{"subitem_text_value":"KODAMA, Koichi"},{"subitem_text_value":"KAWAMURA, Ryo"},{"subitem_text_value":"KOMATSU, Takuma"}]},"item_120_text_32":{"attribute_name":"アイテムID","attribute_value_mlt":[{"subitem_text_value":"KY-18838278-2-15"}]},"item_120_text_4":{"attribute_name":"著者 所属","attribute_value_mlt":[{"subitem_text_value":"埼玉大学大学院理工学研究科"},{"subitem_text_value":"埼玉大学大学院理工学研究科"},{"subitem_text_value":"埼玉大学大学院理工学研究科"},{"subitem_text_value":"株式会社インテリム"},{"subitem_text_value":"株式会社インテリム"}]},"item_120_text_5":{"attribute_name":"著者 所属(別言語)","attribute_value_mlt":[{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"},{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"},{"subitem_text_value":"Graduate School of Science and Engineering, Saitama University"},{"subitem_text_value":"intellium Corp."},{"subitem_text_value":"intellium Corp."}]},"item_120_text_9":{"attribute_name":"年月次","attribute_value_mlt":[{"subitem_text_value":"2010-7"}]},"item_120_version_type_28":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"廣瀬, 卓司"},{"creatorName":"ヒロセ, タクジ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"王, 祥波"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"小玉, 康一"},{"creatorName":"コダマ, コウイチ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"川村, 怜"},{"creatorName":"カワムラ, リョウ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"小松, 拓磨"},{"creatorName":"コマツ, タクマ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-01-24"}],"displaytype":"detail","filename":"KY-18838278-2-15.pdf","filesize":[{"value":"301.2 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"KY-18838278-2-15.pdf","url":"https://sucra.repo.nii.ac.jp/record/16524/files/KY-18838278-2-15.pdf"},"version_id":"f7324d58-27d2-40ca-b250-93a850e7912b"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"aldehyde","subitem_subject_scheme":"Other"},{"subitem_subject":"asymmetric addition","subitem_subject_scheme":"Other"},{"subitem_subject":"chirality control","subitem_subject_scheme":"Other"},{"subitem_subject":"1,3-aminoalcohols","subitem_subject_scheme":"Other"},{"subitem_subject":"cis-(1R,2S)-2-benzamidocyclohexanecarboxylic acid","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"cis-(1R,2S)-2-ベンズアミドシクロヘキサンカルボン酸から誘導した1,3-アミノアルコールを用いた芳香族アルデヒドへのジエチル亜鉛の不斉付加における置換基による不斉制御","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"cis-(1R,2S)-2-ベンズアミドシクロヘキサンカルボン酸から誘導した1,3-アミノアルコールを用いた芳香族アルデヒドへのジエチル亜鉛の不斉付加における置換基による不斉制御"}]},"item_type_id":"120","owner":"3","path":["631"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-07-30"},"publish_date":"2010-07-30","publish_status":"0","recid":"16524","relation_version_is_last":true,"title":["cis-(1R,2S)-2-ベンズアミドシクロヘキサンカルボン酸から誘導した1,3-アミノアルコールを用いた芳香族アルデヒドへのジエチル亜鉛の不斉付加における置換基による不斉制御"],"weko_creator_id":"3","weko_shared_id":-1},"updated":"2023-05-15T18:04:01.509791+00:00"}