{"created":"2023-05-15T15:29:08.422364+00:00","id":18692,"links":{},"metadata":{"_buckets":{"deposit":"619d77a1-c831-4c46-86db-2db2c7fa21b4"},"_deposit":{"created_by":15,"id":"18692","owners":[15],"pid":{"revision_id":0,"type":"depid","value":"18692"},"status":"published"},"_oai":{"id":"oai:sucra.repo.nii.ac.jp:00018692","sets":["94:429:431:432:942"]},"author_link":[],"item_113_alternative_title_1":{"attribute_name":"タイトル（別言語）","attribute_value_mlt":[{"subitem_alternative_title":"Study on filtration of tobacco smoke through packed beds and evaluation for the smoke state and composition of compounds"}]},"item_113_biblio_info_9":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2018","bibliographicIssueDateType":"Issued"}}]},"item_113_date_35":{"attribute_name":"作成日","attribute_value_mlt":[{"subitem_date_issued_datetime":"2019-07-12","subitem_date_issued_type":"Created"}]},"item_113_date_granted_20":{"attribute_name":"学位授与年月日","attribute_value_mlt":[{"subitem_dategranted":"2018-09-21"}]},"item_113_degree_grantor_22":{"attribute_name":"学位授与機関","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_name":"埼玉大学"}],"subitem_degreegrantor_identifier":[{"subitem_degreegrantor_identifier_name":"12401","subitem_degreegrantor_identifier_scheme":"kakenhi"}]}]},"item_113_degree_name_21":{"attribute_name":"学位名","attribute_value_mlt":[{"subitem_degreename":"博士(工学)"}]},"item_113_description_13":{"attribute_name":"形態","attribute_value_mlt":[{"subitem_description":"119ｐ","subitem_description_type":"Other"}]},"item_113_description_24":{"attribute_name":"目次","attribute_value_mlt":[{"subitem_description":"第1 章 序論 ............................................................................................................................... 1\n1.1 研究背景 ....................................................................................................................... 1\n1.1.1 シガレットの成分輸送現象と充填層における機械的濾過 .................................... 1\n1.1.2 たばこ煙のガス-粒子分配測定 ................................................................................ 8\n1.1.3 揮発性粒子の粒径測定とエアロゾル粒子固定化 ................................................. 14\n1.2 本研究の目的 ................................................................................................................. 21\n1.3 本研究の概要と構成 ...................................................................................................... 21\n参考文献 (第1 章) ............................................................................................................... 23\n第2 章 たばこ充填層の機械的濾過に関する研究 ................................................................. 29\n2.1 はじめに ........................................................................................................................ 29\n2.2 実験方法 ........................................................................................................................ 29\n2.2.1 たばこ充填層のサンプル ....................................................................................... 29\n2.2.2 たばこ充填層の刻物性の測定 ................................................................................ 30\n2.2.3 標準粒子による濾過率の測定 ................................................................................ 30\n2.2.4 シガレット燃焼時の濾過率測定 ............................................................................ 31\n2.2.5 成分分析方法 .......................................................................................................... 32\n2.3 結果と考察 .................................................................................................................... 33\n2.3.1 たばこ煙の模擬粒子 ............................................................................................... 33\n2.3.2 充填層既往研究との比較 ....................................................................................... 34\n2.3.3 たばこ充填層へのFitting と濾過モデル ................................................................ 37\n2.3.4 刻のサイズ形状係数およびたばこ充填層の粒度分布係数の濾過式への応用 .... 40\n2.3.5 燃焼時濾過率と予測値の比較 ................................................................................ 44\n2.4 まとめ ............................................................................................................................ 46\n参考文献 (第2 章) ............................................................................................................... 47\n第3 章 たばこ煙のガス-粒子分配測定手法に関する研究 .................................................... 49\n3.1 はじめに ........................................................................................................................ 49\n3.2 実験方法 ........................................................................................................................ 50\n3.2.1 たばこ煙発生方法とサンプル ................................................................................ 50\n3.2.2 デニューダー操作 .................................................................................................. 51\n3.2.3 抽出および成分分析 ............................................................................................... 53\n3.2.4 喫煙試験 .................................................................................................................. 54\n3.2.5 粒径分布測定 .......................................................................................................... 55\n3.2.6 粒子損失およびガス捕集効率測定 ........................................................................ 55\n3.2.7 揮発影響を考慮したガス-粒子分配の解析方法 ................................................... 57\n3.3 結果と考察 .................................................................................................................... 59\n3.3.1 発生粒子の粒径分布 ............................................................................................... 59\n3.3.2 粒子損失 .................................................................................................................. 59\n3.3.3 ニコチンおよびメントールのガス捕集効率 ......................................................... 62\n3.3.4 アニュラーデニューダー内での粒子からの揮発影響 .......................................... 63\n3.3.5 AD-FP 法とフィルターインピンジャー法の結果比較 .......................................... 66\n3.4 まとめ ............................................................................................................................ 68\n参考文献 (第3 章) ............................................................................................................... 70\n第4 章 揮発性粒子の固定化手法および粒径分布測定に関する研究 ................................ 73\n4.1 はじめに ........................................................................................................................ 73\n4.2 実験方法 ........................................................................................................................ 74\n4.2.1 揮発性粒子の発生、エアロゾル溶液、固定化剤 ................................................. 74\n4.2.2 実験系ライン .......................................................................................................... 76\n4.2.3 各種粒径分布計測器の計測条件 ............................................................................ 77\n4.2.4 喫煙回数毎の成分量確認試験 ................................................................................ 79\n4.2.5 エアロゾル溶液と固定化剤の溶解性および溶解度試験 ...................................... 79\n4.2.6 SEM-EDX 解析 ........................................................................................................ 80\n4.2.7 TOF-SIMS 解析 ....................................................................................................... 81\n4.3 結果と考察 .................................................................................................................... 82\n4.3.1 固定化剤添加による成分生成量への影響 ............................................................. 82\n4.3.2 プロピレングリコールおよびグリセリンに対して有効な固定化剤の選定 ........ 82\n4.3.3 各種エアロゾル溶液に対するノナデカン酸の固定化効果 .................................. 85\n4.3.4 固定化剤を増減した際の影響 ................................................................................ 87\n4.3.5 AMS 解析による粒径毎の固定化剤の存在割合 ..................................................... 89\n4.3.6 AMS スペクトル解析による粒径毎のエアロゾル粒子中の成分組成変化 ........... 90\n4.3.7 固定化剤有無による希釈時のSMPS 粒子径測定結果への影響 ........................... 92\n4.3.8 SEM-EDX による固定化効果の確認 ....................................................................... 93\n4.3.9 TOF-SIMS による固定化効果の確認および表面状態解析 .................................... 94\n4.4 まとめ ............................................................................................................................ 97\n参考文献 (第4 章) ............................................................................................................... 98\n第5 章 揮発性粒子のたばこ充填層における濾過特性に関する研究 .............................. 101\n5.1 はじめに ...................................................................................................................... 101\n5.2 実験方法 ...................................................................................................................... 102\n5.2.1 たばこ充填層のサンプル ..................................................................................... 102\n5.2.2 たばこ充填層の刻物性の測定 .............................................................................. 103\n5.2.3 HTP の仕様および濾過率測定 .............................................................................. 103\n5.2.4 抽出および成分分析 ............................................................................................. 104\n5.2.5 粒径分布測定 ........................................................................................................ 105\n5.3 結果と考察 .................................................................................................................. 106\n5.3.1 揮発性粒子の機械的濾過と濾過特異性 .............................................................. 106\n5.3.2 揮発性粒子におけるサイズ形状係数と濾過率の関係性 .................................... 109\n5.3.3 固定化剤添加による揮発性粒子の濾過率への効果 ............................................ 109\n5.4 まとめ ........................................................................................................................... 111\n参考文献 (第5 章) .............................................................................................................. 112\n第6 章 結論 .......................................................................................................................... 113\n6.1 各章の結論 ................................................................................................................... 113\n6.2 今後の課題 ................................................................................................................... 114\n記号一覧 .................................................................................................................................. 115\n本論文に関連する研究業績一覧 ............................................................................................ 118\n謝辞 ......................................................................................................................................... 119","subitem_description_type":"Other"}]},"item_113_description_25":{"attribute_name":"注記","attribute_value_mlt":[{"subitem_description":"主指導教員 : 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