@phdthesis{oai:sucra.repo.nii.ac.jp:00018906,
 author = {孟, 起},
 month = {},
 note = {135 p., Chapter 1. General Introduction   1
1.1 Background   2
1.2 Heat-Registrant Nanodiamond Layers   6
1.3 Topological Polymers   10
1.4 This Study   13

Chapter 2.Materials and Methods   16
2.1 Nanodiamond Preparation   16
2.2 Types of Modified Agents Used in This Study and Their Modification Reaction   16
2.3 Aggregated Particle Size Evaluation of Dispersion Medium   20
2.4 Formation of Single Particle Layer on the Water Surface   20
2.5 Transferring of Organized Particle Layer onto Solid Substrate and Its Evaluation   21
2.6 Preparation and characterization of organo-modified ND   24
2.7 Formation of monolayer on the water surface and estimation of structure and morphology of transferred films  34
2.8 Morphological observation and elucidation of organo-particle arrangement in the integrated layers   34
2.9 Topological Polymers   35
2.10 Structural Estimations of Topological Polymers   35

Chapter 3. Correlation Between Nanodispersion of Organo-Modified Nanodiamond in Solvent and Condensed Behavior of Their Organized Particle Films  38
3.1 Abstract   38
3.2 Evaluation and Calculation of Surface Modification Ratio   39
3.3 Dispersion Behavior of Organo-Modified ND in Polar and/or Nonpolar Solvents   42
3.4 Formation of Single Particle Layers on the Water Surface of Organo-Modified NDs   49
3.5 Characterization of Morphology and Arrangement of Organized Particle Films of Organo-Modified ND on Solid Substrate   52
3.6 Relation between Condensation Behavior at Air/Water Interface and Dispersibility in Solution of Organo-Modified ND   58
3.7 Conclusion   60

Chapter 4. Thermal stability of ordered multi-particle layers of long-chain phosphonate-modified nanodiamond with superior heat-resistance   62
4.1 Abstract   62
4.2 Solid-State Structure and Monolayer Formation of Organo-Modified ND   63
4.3 Multi-Particle Layer Structure of Organo-Modified ND   68
4.4 Discussion   73
4.5 Conclusion   81

Chapter 5. Topological "Interfacial" Polymer Chemistry-Dependency of Polymer "Shape" on Surface Morphology and Stability of Layer Structures when Heating Organized Molecular Films of Cyclic and Linear Block Copolymers of n-Butyl Acrylate-Ethylene Oxide-   83
5.1 Abstract   83
5.2 Monolayer Formation of Topological Polymers at Air/Water Interface   85
5.3 Monolayer Morphology of Topological Polymers on Solid Substrate   94
5.4 Molecular Arrangement of Topological Polymers in Multilayers   99
5.5 Conclusion   104

Chapter 6. Concluding Remarks   106

References and Notes   110

Publications   128

Acknowledgements   134, 指導教員 : 藤森厚裕, text, application/pdf},
 school = {埼玉大学},
 title = {超薄分子組織化膜技術の新潮流 : "有機化無機ナノ粒子"と"高分子トポロジー化学"への展開},
 year = {2019},
 yomi = {モウ, キ}
}